The study of the conditions for the coprecipitation of calcium hydroxylapatite, titanium hydroxide, and collagen with ammonia from aqueous solutions

被引:0
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作者
Ezhova, ZA [1 ]
Orlovskii, VP [1 ]
Koval', EM [1 ]
机构
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
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D O I
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The interaction in the system CaCl2-TiCl4(HCl)-(NH4)(2)HPO4-NH3-H2O-collagen at 25 degrees C is studied by the solubility (Tanaev's residual concentrations) method and pH measurements. The conditions for the coprecipitation of calcium and titanium hydroxylapatites are found. Solid phases of calcium hydroxylapatite, titanium hydroxide, and collagen are obtained. The solid phases and the products of their calcining at 950 degrees C are identified by chemical and X-ray phase analyses and IR spectroscopy. Homogeneous phases containing mixtures of Ca-10(PO4)(6)(OH)(2) and TiO2 (rutile) are obtained.
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页码:651 / 655
页数:5
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