Wall-to-bed mass transfer in three-phase fluidized beds in the absence and presence of a composite promoter

Wall-to-bed mass transfer coefficients were computed in a three-phase fluidized bed in plain annuli and in the absence and presence of a helicoidal tape wound on a coaxial central rod of varying diameters using electrochemical technique. Class spheres were used as solid phase, an electrolyte (equimolar ferri-ferrocyanide solution) as liquid-phase and nitrogen as gaseous phase. The test section was an acrylic cylindrical column of 6.73 cm i.d. Limiting current measurements were made at point copper electrodes fixed nosh with the test section, which facilitated the computation of wall-to-bed mass transfer coefficients. Augmentation in wall-to-bed mass transfer coefficient was found to be significant with increased liquid and gas velocities, and particle diameter. The presence of composite promoter showed significant improvements in the wall-to-bed mass transfer coefficients. The data on wall-to-bed mass transfer coefficient were correlated in terms of Coulburn j(D) factor, individual phase holdups, particle Reynolds number and geometrical parameters of the composite promoter as j(D)epsilon(L) = 0. 14[((Re(p)epsilon)/(epsilon(L)(1- epsilon)))(1 + (p/D(c)))](-0.23). (C) 2009 Elsevier B.V. All rights reserved.