Green synthesis of peptide-templated fluorescent copper nanoclusters for temperature sensing and cellular imaging

被引:115
作者
Huang, Hong [1 ]
Li, Hua [1 ]
Wang, Ai-Jun [1 ]
Zhong, Shu-Xian [1 ]
Fang, Ke-Ming [1 ]
Feng, Jiu-Ju [1 ]
机构
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Coll Geog & Environm Sci, Jinhua 321004, Peoples R China
基金
中国国家自然科学基金;
关键词
GOLD NANOCLUSTERS; CLUSTERS; EMISSION; NUCLEI; PROBE; DOTS;
D O I
10.1039/c4an01757a
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A simple and green approach was developed for the preparation of fluorescent Cu nanoclusters (NCs) using the artificial peptide CLEDNN as a template. The as-synthesized Cu NCs exhibited a high fluorescence quantum yield (7.3%) and good stability, along with excitation and temperature dependent fluorescent properties, which could be employed for temperature sensing. Further investigations demonstrated low toxicity of Cu NCs for cellular imaging.
引用
收藏
页码:6536 / 6541
页数:6
相关论文
共 29 条
[1]   Serial Silver Clusters Biomineralized by One Peptide [J].
Cui, Yanyan ;
Wang, Yaling ;
Liu, Ru ;
Sun, Zhipeng ;
Wei, Yueteng ;
Zhao, Yuliang ;
Gao, Xueyun .
ACS NANO, 2011, 5 (11) :8684-8689
[2]   Peptide-templated synthesis of wavelength-tunable fluorescent gold nanoparticles [J].
Feng, Jiu-Ju ;
Huang, Hong ;
Zhou, Dan-Ling ;
Cai, Lin-Yi ;
Tu, Qi-Qi ;
Wang, Ai-Jun .
JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (31) :4720-4725
[3]   Blue-Emitting Copper Nanoclusters Synthesized in the Presence of Lysozyme as Candidates for Cell Labeling [J].
Ghosh, Rama ;
Sahoo, Amaresh Kumar ;
Ghosh, Siddhartha Sankar ;
Paul, Anumita ;
Chattopadhyay, Arun .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (06) :3822-3828
[4]   Peptide-templated gold nanoclusters as a novel label-free biosensor for the detection of protease activity [J].
Gu, Yi ;
Wen, Qian ;
Kuang, Yongqing ;
Tang, Lijuan ;
Jiang, Jianhui .
RSC ADVANCES, 2014, 4 (27) :13753-13756
[5]   Stable Cu nanoclusters: from an aggregation-induced emission mechanism to biosensing and catalytic applications [J].
Jia, Xiaofang ;
Yang, Xuan ;
Li, Jing ;
Liab, Dongyue ;
Wang, Erkang .
CHEMICAL COMMUNICATIONS, 2014, 50 (02) :237-239
[6]   Cu Nanoclusters with Aggregation Induced Emission Enhancement [J].
Jia, Xiaofang ;
Li, Jing ;
Wang, Erkang .
SMALL, 2013, 9 (22) :3873-3879
[7]   DNA-Hosted Copper Nanoclusters for Fluorescent Identification of Single Nucleotide Polymorphisms [J].
Jia, Xiaofang ;
Li, Jing ;
Han, Lei ;
Ren, Jiangtao ;
Yang, Xuan ;
Wang, Erkang .
ACS NANO, 2012, 6 (04) :3311-3317
[8]   Quantum sized, thiolate-protected gold nanoclusters [J].
Jin, Rongchao .
NANOSCALE, 2010, 2 (03) :343-362
[9]   Microwave-assisted polyol synthesis of copper nanocrystals without using additional protective agents [J].
Kawasaki, Hideya ;
Kosaka, Yuka ;
Myoujin, Yuki ;
Narushima, Takashi ;
Yonezawa, Tetsu ;
Arakawa, Ryuichi .
CHEMICAL COMMUNICATIONS, 2011, 47 (27) :7740-7742
[10]   A temperature sensor based on CdTe quantum dots-layered double hydroxide ultrathin films via layer-by-layer assembly [J].
Liang, Ruizheng ;
Tian, Rui ;
Shi, Wenying ;
Liu, Zhihui ;
Yan, Dongpeng ;
Wei, Min ;
Evans, David G. ;
Duan, Xue .
CHEMICAL COMMUNICATIONS, 2013, 49 (10) :969-971