Controlled polystyrene brushes grown on AFM tip

被引：13

作者：

Devaux, C ^{[1
]}

Chapel, JP ^{[1
]}

机构：

[1] Univ Lyon 1, ISTIL, Polymer Mat & Biomat Lab, F-69622 Villeurbanne, France

来源：

EUROPEAN PHYSICAL JOURNAL E | 2003年 / 10卷 / 01期

关键词：

D O I：

10.1140/epje/e2003-00010-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report here the first successful growth of Polystyrene brushes directly from the apex of a conventional AFM tip using a Langmuir-Blodgett deposition technique [1,2] associated with a controlled free radical polymerization. The efficiency of the grafting together with the possibility to form multi-layers are checked through AFM force measurements between a bare or functionalized tip and a silicon wafer in water or xylene.

引用

页码：77 / 81

页数：5

共 36 条

[11]

2-C

[12] Controlled graft polymerization of methyl methacrylate on silicon substrate by the combined use of the Langmuir-Blodgett and atom transfer radical polymerization techniques [J].

Ejaz, M ;

Yamamoto, S ;

Ohno, K ;

Tsujii, Y ;

Fukuda, T .

MACROMOLECULES, 1998, 31 (17) :5934-5936

[13] Influence of headgroup cross-linking on chain packing in Langmuir monolayers of n-alkyltrialkoxysilanes [J].

Fontaine, P ;

Goldmann, M ;

Rondelez, F .

LANGMUIR, 1999, 15 (04) :1348-1352

[14] Contact of two carbon surfaces covered with a dispersant polymer [J].

Georges, E ;

Georges, JM ;

Hollinger, S .

LANGMUIR, 1997, 13 (13) :3454-3463

[15] Surface initiation of living radical polymerization for growth of tethered chains of low polydispersity [J].

Huang, X ;

Wirth, MJ .

MACROMOLECULES, 1999, 32 (05) :1694-1696

[16] Controlled synthesis of polymer brushes by "Living" free radical polymerization techniques [J].

Husseman, M ;

Malmström, EE ;

McNamara, M ;

Mate, M ;

Mecerreyes, D ;

Benoit, DG ;

Hedrick, JL ;

Mansky, P ;

Huang, E ;

Russell, TP ;

Hawker, CJ .

MACROMOLECULES, 1999, 32 (05) :1424-1431

[17]

ILEY TW, 1998, MACROMOLECULES, V31, P4297

[18] Surface initiated living cationic polymerization of 2-oxazolines [J].

Jordan, R ;

Ulman, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (02) :243-247

[19]

Klein J, 1998, ACTA POLYM, V49, P617, DOI 10.1002/(SICI)1521-4044(199810)49:10/11<617::AID-APOL617>3.3.CO

[20]

2-#

← 1 2 3 4 →