Telomerisation of 1,3-butadiene with glycerol under aqueous biphasic conditions: Influence of the reaction conditions on the products distribution

被引：21

作者：

Bigot, Sandra ^{[1
]}

Lai, Jonathan ^{[1
]}

Suisse, Isabelle ^{[1
]}

Sauthier, Mathieu ^{[1
]}

Mortreux, Andre ^{[1
]}

Castanet, Yves ^{[1
]}

机构：

[1] Univ Lille Nord France, UMR CNRS 8181, Unite Catalyse & Chim Solide, ENSCL, F-59652 Villeneuve Dascq, France

来源：

APPLIED CATALYSIS A-GENERAL | 2010年 / 382卷 / 02期

关键词：

Telomerisation; Glycerol; Butadiene; Palladium catalysis; Octadienyl ethers; BUTADIENE TELOMERIZATION; CATALYZED TELOMERIZATION; PALLADIUM(0) COMPLEXES; D-XYLOSE; ALCOHOLS; WATER; LIGANDS; TRIPHENYLPHOSPHINE; BUTA-1,3-DIENE; METHANOL;

D O I：

10.1016/j.apcata.2010.04.039

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The palladium-catalyzed telomerisation of butadiene with glycerol has been studied under aqueous biphasic conditions both in the presence of a liquid phase of butadiene and under gaseous atmosphere of butadiene. In this last case, gaseous butadiene was continuously added during the whole reaction time keeping constant its pressure. Most of the products formed have been fully characterized. The influence of various experimental parameters has been checked with the aim to obtain high activities and selectivities either into mono-, di- or tritelomers. (c) 2010 Elsevier B.V. All rights reserved.

引用

页码：181 / 189

页数：9

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