Electrical properties and ageing characteristics of BaTiO3 ceramics doped by single dopants

BaTiO3 ceramics doped by single dopants Of SM2O3, Ho2O3, Bi2O3, La2O3, CeO2 and Ta2O5, respectively, were prepared and aged in air. The room-temperature resistivity was measured and the relationship between resistivity change versus ageing time was determined. The electrical resistivity of Bi- and Ta-doped samples decreases at the early ageing stage, and then increases with the ageing time; the other doped ceramics display a monotonous increase of the resistivity with ageing time. The electrical properties and ageing characteristics are analyzed by considering interior oxidation and reduction reactions and the electronegativity of the doping elements. (C) 2004 Elsevier Ltd. All rights reserved.