Solution processing of CuIn(S,Se)2 and Cu(In,Ga)(S,Se)2 thin film solar cells using metal chalcogenide precursors

被引:31
作者
Arnou, Panagiota [1 ]
Cooper, Carl S. [2 ]
Ulicna, Sona [1 ]
Abbas, Ali [1 ]
Eeles, Alex [1 ]
Wright, Lewis D. [1 ]
Malkov, Andrei V. [2 ]
Walls, John M. [1 ]
Bowers, Jake W. [1 ]
机构
[1] Loughborough Univ, Wolfson Sch Mech Elect & Mfg Engn, CREST, Loughborough LE11 3TU, Leics, England
[2] Loughborough Univ, Dept Chem, Loughborough LE11 3TU, Leics, England
基金
英国工程与自然科学研究理事会;
关键词
Chalcopyrite; CIGS; Gallium content; Thin-film solar cells; Spray-coating; Solution processing; EFFICIENCY; LAYERS;
D O I
10.1016/j.tsf.2016.10.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In order to realize the true low cost potential of Cu(In,Ga)(S,Se)(2) (CIGS) thin film solar cells, high performance needs to be combined with simple and easily controllable atmospheric-based deposition processes. A molecular solution-based approach for CIGS deposition is proposed, using metal chalcogenide precursors dissolved in an amine-thiol solvent combination. CIGS thin films were sprayed with varying Ga content and the sprayed films were incorporated into solar cells. The effect of the Ga content on the material and device properties is investigated. A champion power conversion efficiency of 9.8% (active area) was achieved, which highlights the potential of this methodology. (C) 2016 The Authors. Published by Elsevier B.V.
引用
收藏
页码:76 / 80
页数:5
相关论文
共 23 条
[1]  
Arnou P., 2015, 42 IEEE PHOT SPEC C, P1
[2]   Hydrazine-Free Solution-Deposited CuIn(S,Se)2 Solar Cells by Spray Deposition of Metal Chalcogenides [J].
Arnou, Panagiota ;
van Hest, Maikel F. A. M. ;
Cooper, Carl S. ;
Malkov, Andrei V. ;
Walls, John M. ;
Bowers, Jake W. .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (19) :11893-11897
[3]   Solution-processed CuIn(S, Se)2 absorber layers for application in thin film solar cells [J].
Arnou, Panagiota ;
Cooper, Carl S. ;
Malkov, Andrei V. ;
Bowers, Jake W. ;
Walls, John M. .
THIN SOLID FILMS, 2015, 582 :31-34
[4]   A new approach to high-efficiency solar cells by band gap grading in Cu(In,Ga)Se2 chalcopyrite semiconductors [J].
Dullweber, T ;
Hanna, G ;
Rau, U ;
Schock, HW .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 67 (1-4) :145-150
[5]   Sulfide Nanocrystal Inks for Dense Cu(In1-xGax)(S1-ySey)2 Absorber Films and Their Photovoltaic Performance [J].
Guo, Qijie ;
Ford, Grayson M. ;
Hillhouse, Hugh W. ;
Agrawal, Rakesh .
NANO LETTERS, 2009, 9 (08) :3060-3065
[6]   Synthesis of Cu(In,Ga)(S,Se)2 thin films using an aqueous spray-pyrolysis approach, and their solar cell efficiency of 10.5% [J].
Hossain, Md. Anower ;
Zhang Tianliang ;
Keat, Lee Kian ;
Li Xianglin ;
Prabhakar, Rajiv R. ;
Batabyal, Sudip K. ;
Mhaisalkar, Subodh G. ;
Wong, Lydia H. .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (08) :4147-4154
[7]   Electrodeposition based synthesis of S-rich CuIn(S,Se)2 layers for photovoltaic applications: Raman scattering analysis of electrodeposited CuInSe2 precursors [J].
Izquierdo-Roca, V. ;
Fontane, X. ;
Alvarez-Garcia, J. ;
Calvo-Barrio, L. ;
Perez-Rodriguez, A. ;
Morante, J. R. ;
Jaime-Ferrer, J. S. ;
Saucedo, E. ;
Grand, P. P. ;
Bermudez, V. .
THIN SOLID FILMS, 2009, 517 (07) :2163-2166
[8]   Properties of Cu(In,Ga)Se2 solar cells with new record efficiencies up to 21.7% [J].
Jackson, Philip ;
Hariskos, Dimitrios ;
Wuerz, Roland ;
Kiowski, Oliver ;
Bauer, Andreas ;
Friedlmeier, Theresa Magorian ;
Powalla, Michael .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2015, 9 (01) :28-31
[9]   Thin film deposition methods for CulnSe2 solar cells [J].
Kemell, M ;
Ritala, M ;
Leskelä, M .
CRITICAL REVIEWS IN SOLID STATE AND MATERIALS SCIENCES, 2005, 30 (01) :1-31
[10]   Approaches to flexible CIGS thin-film solar cells [J].
Kessler, F ;
Herrmann, D ;
Powalla, M .
THIN SOLID FILMS, 2005, 480 :491-498