Some hydrogels having novel molecular structures

被引:124
作者
Johnson, Jeremiah A. [1 ]
Turro, Nicholas J. [1 ]
Koberstein, Jeffrey T. [2 ]
Mark, James E. [2 ]
机构
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
[2] Columbia Univ, Dept Chem Engn, New York, NY 10027 USA
基金
美国国家科学基金会;
关键词
Hydrogels; Slide-ring gels; Double-network gels; Nanocomposite gels; Photoactive hydrogels; Mechanical properties; Toughness; DOUBLE-NETWORK HYDROGEL; TO-GLOBULE TRANSITION; SLIDE-RING GELS; MECHANICAL-PROPERTIES; HIGH-STRENGTH; NANOCOMPOSITE HYDROGELS; POLYMER NETWORKS; CRACK TIPS; CLAY; BEHAVIOR;
D O I
10.1016/j.progpolymsci.2009.12.002
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Hydrogels are important materials for a variety of applications, particularly biomedical devices, but they generally have poor mechanical properties since they consist predominantly of water held in place by a relatively fragile polymer network. This brief review describes a few novel methods to control or improve the mechanical properties of hydrogels including slide-ring gels, double-network gels, nanocomposite gels, and photoactive gels. Our goal is to encourage more researchers to be aware of and to exploit these methods. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:332 / 337
页数:6
相关论文
共 111 条
[51]   Photodegradable Hydrogels for Dynamic Tuning of Physical and Chemical Properties [J].
Kloxin, April M. ;
Kasko, Andrea M. ;
Salinas, Chelsea N. ;
Anseth, Kristi S. .
SCIENCE, 2009, 324 (5923) :59-63
[52]  
Kolb HC, 2001, ANGEW CHEM INT EDIT, V40, P2004, DOI 10.1002/1521-3773(20010601)40:11<2004::AID-ANIE2004>3.3.CO
[53]  
2-X
[54]  
KOPECEK J, 2009, CONTACT LENSES, V47, P5929
[55]   Responsive hydrogel layers-from synthesis to applications [J].
Kuckling, Dirk .
COLLOID AND POLYMER SCIENCE, 2009, 287 (08) :881-891
[56]   Biomimetic design of reversibly unfolding cross-linker to enhance mechanical properties of 3D network polymers [J].
Kushner, Aaron M. ;
Gabuchian, Vahe ;
Johnson, Evan G. ;
Guan, Zhibin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (46) :14110-+
[57]   Polyelectrolyte gels-fundamentals and applications [J].
Kwon, Hyuck Joon ;
Osada, Yoshihito ;
Gong, Jian Ping .
POLYMER JOURNAL, 2006, 38 (12) :1211-1219
[58]   Effect of montmorillonite on the swelling behavior and drug-release behavior of nanocomposite hydrogels [J].
Lee, WF ;
Fu, YT .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 89 (13) :3652-3660
[59]  
LI J, 2008, POLYM SCI, V222, P79
[60]   A photolabile hydrogel for guided three-dimensional cell growth and migration [J].
Luo, Y ;
Shoichet, MS .
NATURE MATERIALS, 2004, 3 (04) :249-253