Zn/Fe mixed oxide: Heterogeneous catalyst for the synthesis of dimethyl carbonate from methyl carbamate and methanol

被引：30

作者：

Wang, Dengfeng ^{[1
,2
]}

Zhang, Xuelan ^{[1
,2
]}

Gao, Yangyan ^{[1
,2
]}

Xiao, Fukui ^{[1
]}

Wei, Wei ^{[1
]}

Sun, Yuhan ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2010年 / 11卷 / 05期

关键词：

Dimethyl carbonate; Methyl carbamate; Methanol; Zn/Fe mixed oxide; UREA; ALCOHOLYSIS; DIOXIDE; ZNO;

D O I：

10.1016/j.catcom.2009.11.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of Zn-Fe-O mixed oxides were prepared for the synthesis of dimethyl carbonate (DMC) from methyl carbamate and methanol. X-ray diffraction revealed that zinc ferrite crystal phase appeared and changed with different Zn/Fe molar ratio. The DMC yield could reach 30.7% under suitable conditions. In addition, elemental chemical analysis and the reusability test indicated that these catalysts presented good stability. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：430 / 433

页数：4

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