One-Step Construction of Two Different Kinds of Pores in a 2D Covalent Organic Framework

被引：412
作者：
Zhou, Tian-You [1 ]
Xu, Shun-Qi [1 ]
Wen, Qiang [1 ]
Pang, Zhong-Fu [1 ]
Zhao, Xin [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet & Self Assembly Chem Organ Funct, Shanghai 200032, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 45期
基金：
中国国家自然科学基金;
关键词：
CRYSTALLINE; IMINE; STABILITY; CATALYSIS;
D O I：
10.1021/ja5092936
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Covalent organic frameworks (COFs) are crystalline porous materials bearing microporous or mesoporous pores. The type and size of pores play crucial roles in regulating the properties of COFs. In this work, a novel COF, which bears two different kinds of ordered pores with controllable sizes: one within microporous range (7.1 angstrom) and the other in mesoporous range (26.9 angstrom), has been constructed via one-step synthesis. The structure of the dual-pore COF was confirmed by PXRD investigation, nitrogen adsorptiondesorption study, and theoretical calculations.
引用
收藏
页码：15885 / 15888
页数：4
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