Rate coefficients for electron-impact rotational excitation of H+3 and H3O+

Molecular R-matrix calculations are performed to obtain rotational excitation rate coefficients for electron collisions with the symmetric-top ions H(3)(+) and H(3)O(+) up to electron temperatures of 10 000 K. De-excitation rates and critical electron densities are also given. It is shown that short-range interactions, which are ignored in the standard Coulomb-Born theory, are crucial for studying electron-impact rotational excitation of molecular ions. In particular, our calculations show that electron collisions could help to create and maintain the predicted population inversion between the (J, K)=(4,4) and (3,1) levels of H(3)(+) and populate the rotational levels of H(3)O(+) up to the (4,1) level.