Copper catalyzed oxidative deamination of Betti bases: an efficient approach for benzoylation/formylation of naphthols and phenols

被引：35
作者：
Deb, Mohit L. [1 ]
Pegu, Choitanya Dev [1 ]
Borpatra, Paran J. [1 ]
Baruah, Pranjal K. [1 ]
机构：
[1] Gauhati Univ, Dept Appl Sci, GUIST, Gauhati 781014, Assam, India
来源：
RSC ADVANCES | 2016年 / 6卷 / 46期
关键词：
C-H BOND; DEHYDROGENATIVE COUPLING REACTIONS; SURFACTANT-COMBINED CATALYST; MANNICH-TYPE REACTIONS; FRIES REARRANGEMENT; TERTIARY-AMINES; ENANTIOSELECTIVE ADDITION; BENZOPHENONE DERIVATIVES; MULTICOMPONENT SYNTHESIS; FACILE SYNTHESIS;
D O I：
10.1039/c6ra04567g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient route for benzoylation or formylation of naphthols/phenols is developed via oxidative deamination of Betti bases. A copper salt catalyst with TBHP as an oxidant is used. Water is used as a reagent as well as solvent. The reaction proceeds through a regioselective radical pathway. Most importantly, the position of acylation is unambiguous. The method is also applicable to non-hydroxy substrates.
引用
收藏
页码：40552 / 40559
页数：8
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