The effect of self-sorting and co-assembly on the mechanical properties of low molecular weight hydrogels

被引：100

作者：

Colquhoun, Catherine ^{[1
]}

Draper, Emily R. ^{[1
]}

Eden, Edward G. B. ^{[1
]}

Cattoz, Beatrice N. ^{[2
]}

Morris, Kyle L. ^{[3
]}

Chen, Lin ^{[1
]}

McDonald, Tom O. ^{[1
]}

Terry, Ann E. ^{[4
]}

Griffiths, Peter C. ^{[2
]}

Serpell, Louise C. ^{[3
]}

Adams, Dave J. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Greenwich, Sch Sci, Chatham ME4 4TB, Kent, England

[3] Univ Sussex, Sch Life Sci, Falmer BN1 9QG, E Sussex, England

[4] Rutherford Appleton Lab, Sci & Technol Facil Council, Didcot OX11 0QX, Oxon, England

来源：

NANOSCALE | 2014年 / 6卷 / 22期

基金：

英国工程与自然科学研究理事会;

关键词：

SUPRAMOLECULAR HYDROGELS; COMPONENT SELECTION; GELATORS; GELS; SURFACTANTS; NETWORKS; INSIGHTS; SYSTEMS;

D O I：

10.1039/c4nr04039b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-sorting in low molecular weight hydrogels can be achieved using a pH triggered approach. We show here that this method can be used to prepare gels with different types of mechanical properties. Cooperative, disruptive or orthogonal assembled systems can be produced. Gels with interesting behaviour can be also prepared, for example self-sorted gels where delayed switch-on of gelation occurs. By careful choice of gelator, co-assembled structures can also be generated, which leads to synergistic strengthening of the mechanical properties.

引用

页码：13719 / 13725

页数：7

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