Graphene materials from microwave-derived carbon precursors

被引:15
作者
Gonzalez, Zoraida [1 ]
Acevedo, Beatriz [2 ]
Predeanu, Georgeta [3 ]
Axinte, Sorin M. [4 ]
Dragoescu, Marius-Florin [4 ]
Slavescu, Valerica [3 ]
Fernandez, Juan J. [5 ]
Granda, Marcos [1 ]
Gryglewicz, Grazyna [6 ]
Melendi-Espina, Sonia [2 ]
机构
[1] CSIC, INCAR, Inst Ciencia & Tecnol Carbono, Francisco Pintado Fe 26, Oviedo 33011, Spain
[2] Univ East Anglia, Sch Engn, Norwich Res Pk, Norwich NR4 7TJ, Norfolk, England
[3] Univ Politech Bucharest, Fac Appl Chem & Mat Sci, Res Ctr Environm Protect & Ecofriendly Technol, 1 Polizu St, Bucharest 011061, Romania
[4] Claudiu TopRom SRL, Bucharest, Romania
[5] Ind Quim Nalon SA, Trubia, Spain
[6] Wroclaw Univ Sci & Technol, Dept Proc Engn & Technol Polymer & Carbon Mat, Gdanska 7-9, PL-50344 Wroclaw, Poland
关键词
Microwave heating; Conventional heating; Carbon precursors; Energy saving; Graphene materials; ANTHRACENE OIL; RAMAN; TEMPERATURES; PURIFICATION; REDUCTION; NANOTUBES; GRAPHITE; COAL; XRD;
D O I
10.1016/j.fuproc.2021.106803
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Anthracene oil has been used as raw material for the production of carbon precursors via conventional and microwave technologies. Cokes with comparable characteristics have been obtained, suggesting that their structural order is primarily reliant on the precursor rather the heating method. However, microwave route is a more energy efficient process, achieving electricity savings of up to 60%. Furthermore, graphites produced from microwave-derived precursors show an excellent graphitization degree, which makes them appropriate starting resources for the synthesis of graphene-like materials with similar characteristics to those obtained from conventional means. Therefore, microwave-assisted heating approach appears to be a suitable and energy saving alternative for the production of carbon precursors.
引用
收藏
页数:7
相关论文
共 34 条
[1]   FINE-STRUCTURE INVESTIGATIONS OF DIAMOND AND DIAMOND-LIKE CARBON-FILMS USING RAMAN-SPECTROSCOPY [J].
ABELLO, L ;
LUCAZEAU, G ;
ANDRE, B ;
PRIEM, T .
DIAMOND AND RELATED MATERIALS, 1992, 1 (5-6) :512-518
[2]   Tuning graphene properties by a multi-step thermal reduction process [J].
Alvarez, Patricia ;
Blanco, Clara ;
Santamaria, Ricardo ;
Blanco, Patricia ;
Gonzalez, Zoraida ;
Fernandez-Garcia, Laura ;
Sierra, Uriel ;
Granda, Marcos ;
Paez, Antonio ;
Menendez, Rosa .
CARBON, 2015, 90 :160-163
[3]   Preparation of Low Toxicity Pitches by Thermal Oxidative Condensation of Anthracene Oil [J].
Alvarez, Patricia ;
Granda, Marcos ;
Sutil, Juan ;
Santamaria, Ricardo ;
Blanco, Clara ;
Menendez, Rosa ;
Jose Fernandez, Juan ;
Antonio Vina, Jose .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2009, 43 (21) :8126-8132
[4]   Comparative XRD, Raman, and TEM Study on Graphitization of PBO-Derived Carbon Fibers [J].
Beatriz Vazquez-Santos, M. ;
Geissler, Erik ;
Laszlo, Krisztina ;
Rouzaud, Jean-Noel ;
Martinez-Alonso, Amelia ;
Tascon, Juan M. D. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (01) :257-268
[5]   A comparative study of the composition of anthracene oil polymerized by different treatments [J].
Bermejo, J ;
Menéndez, R ;
Fernández, AL ;
Granda, M ;
Suelves, I ;
Herod, AA ;
Kandiyoti, R .
FUEL, 2001, 80 (15) :2155-2162
[6]   Effects of thermal treatment on the composition and properties of air-blown anthracene oils [J].
Bermejo, J ;
Fernández, AL ;
Granda, M ;
Rubiera, F ;
Suelves, I ;
Menéndez, R .
FUEL, 2001, 80 (09) :1229-1238
[7]   Synthesis of graphene [J].
Bhuyan M.S.A. ;
Uddin M.N. ;
Islam M.M. ;
Bipasha F.A. ;
Hossain S.S. .
International Nano Letters, 2016, 6 (2) :65-83
[8]   Critical temperatures in the synthesis of graphene-like materials by thermal exfoliation-reduction of graphite oxide [J].
Botas, Cristina ;
Alvarez, Patricia ;
Blanco, Clara ;
Santamaria, Ricardo ;
Granda, Marcos ;
Dolores Gutierrez, M. ;
Rodriguez-Reinoso, Francisco ;
Menendez, Rosa .
CARBON, 2013, 52 :476-485
[9]   A brief overview on synthesis and applications of graphene and graphene-based nanomaterials [J].
Coros, Maria ;
Pogacean, Florina ;
Magerusan, Lidia ;
Socaci, Crina ;
Pruneanu, Stela .
FRONTIERS OF MATERIALS SCIENCE, 2019, 13 (01) :23-32
[10]  
Drzal L.T., 2006, US-Application, Patent No. 20060241237