The use of TiO2 nanoparticles to enhance CO2 absorption

被引：45

作者：

Zhang, Yu ^{[1
]}

Zhao, Bo ^{[1
]}

Jiang, Jiazong ^{[2
]}

Zhuo, Yuqun ^{[1
]}

Wang, Shujuan ^{[1
]}

机构：

[1] Tsinghua Univ, Beijing Key Lab Utilizat & Reduct Technol CO2, Minist Educ, Key Lab Thermal Sci & Power Engn, Beijing 100084, Peoples R China

[2] North China Elect Power Univ, Minist Educ, Key Lab Condit Monitoring & Control Power Plant E, Beijing 102206, Peoples R China

来源：

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL | 2016年 / 50卷

基金：

中国国家自然科学基金;

关键词：

CO2; absorption; Nanofluid; Mass transfer enhancement; Mass transfer model; MASS-TRANSFER; HEAT-TRANSFER; THERMAL-CONDUCTIVITY; BROWNIAN-MOTION; NANOFLUID FLOW; MODEL; SIMULATION; PARTICLES; PERFORMANCE; SULFIDE;

D O I：

10.1016/j.ijggc.2016.04.014

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The enhancement of absorption of CO2 by propylene carbonate in the presence of TiO2 nanoparticles was investigated. The influences of solids loading and particle size of TiO2 nanoparticles on the absorption rate were studied experimentally. The results show that the gas absorption rate can be enhanced significantly in the presence of TiO2 nanoparticles. The CO2 absorption enhancement factor firstly increases and then decreases with the increases of solids loadings, which proves the existence of optimal solids loading. The particle size is also a main factor, which affects CO2 absorption enhancement factor. As the particle size increases, the optimal solids loading gradually increases. A three-dimensional instantaneous numerous particle di-mechanism model based on the shuttle mechanism as well as a micro-convection mechanism was developed. The results calculated by the model are close to the experimental results, which showed the model can predict experimental data very well. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：49 / 56

页数：8

共 22 条

[1] HEAT AND MASS TRANSFER FROM SINGLE SPHERES IN STOKES FLOW
ACRIVOS, A
TAYLOR, TD
[J]. PHYSICS OF FLUIDS, 1962, 5 (04) : 387 - 394
[2] THE EFFECT OF ACTIVATED CARBON LOADING ON OXYGEN ABSORPTION INTO AQUEOUS SODIUM SULFIDE SOLUTIONS IN A SLURRY REACTOR
ALPER, E
OZTURK, S
[J]. CHEMICAL ENGINEERING JOURNAL AND THE BIOCHEMICAL ENGINEERING JOURNAL, 1986, 32 (02): : 127 - 130
[3] A one-dimensional instationary heterogeneous mass transfer model for gas absorption in multiphase systems
Brilman, DWF
van Swaaij, WPM
Versteeg, GF
[J]. CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 1998, 37 (06) : 471 - 488
[4] The application of fine TiO2 particles for enhanced gas absorption
Dagaonkar, MV
Heeres, HJ
Beenackers, AACM
Pangarkar, VG
[J]. CHEMICAL ENGINEERING JOURNAL, 2003, 92 (1-3) : 151 - 159
[5] Absorption of hydrogen sulfide into aqueous solutions of ferric nitrilotriacetic acid: local auto-catalytic effects
Demmink, JF
Mehra, A
Beenackers, AACM
[J]. CHEMICAL ENGINEERING SCIENCE, 2002, 57 (10) : 1723 - 1734
[6] Huang Jianbin, 2002, IND GAS MANUAL, P110
[7] Experimental study of CO2 absorption in aqueous MEA and MDEA solutions enhanced by nanoparticles
Jiang, Jiazong
Zhao, Bo
Zhuo, Yuqun
Wang, Shujuan
[J]. INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2014, 29 : 135 - 141
[8] The effect of nano-particles on the bubble absorption performance in a binary nanofluid
Kim, JK
Jung, JY
Kang, YT
[J]. INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2006, 29 (01): : 22 - 29
[9] Enhanced mass transport in nanofluids
Krishnamurthy, S
Lhattacharya, P
Phelan, PE
Prasher, RS
[J]. NANO LETTERS, 2006, 6 (03) : 419 - 423
[10] AN EDDY CELL MODEL OF MASS TRANSFER INTO SURFACE OF A TURBULENT LIQUID
LAMONT, JC
SCOTT, DS
[J]. AICHE JOURNAL, 1970, 16 (04) : 513 - +

← 1 2 3 →