An active ferrocenyl triarylphosphine for palladium-catalyzed Suzuki-Miyaura cross-coupling of aryl halides

被引:65
作者
Kwong, FY [1 ]
Chan, KS
Yeung, CH
Chan, ASC
机构
[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Inst Mol Technol Drug Discovery & Synth, Open Lab Chirotechnol, Hong Kong, Hong Kong, Peoples R China
[2] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
关键词
D O I
10.1039/b407661c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pd-catalyzed Suzuki-Miyaura reaction of aryl chlorides was accomplished through the use of an active ferrocene-based triarylphosphine ligand. This air- and moisture-stable ligand was found to be effective for the cross-coupling of aryl halides at room temperature to 115degreesC.
引用
收藏
页码:2336 / 2337
页数:2
相关论文
共 37 条
[31]  
Sakai M, 1998, ANGEW CHEM INT EDIT, V37, P3279, DOI 10.1002/(SICI)1521-3773(19981217)37:23<3279::AID-ANIE3279>3.0.CO
[32]  
2-M
[33]   A rationally designed universal catalyst for Suzuki-Miyaura coupling processes [J].
Walker, SD ;
Barder, TE ;
Martinelli, JR ;
Buchwald, SL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (14) :1871-1876
[34]  
Wolfe JP, 1999, ANGEW CHEM INT EDIT, V38, P2413, DOI 10.1002/(SICI)1521-3773(19990816)38:16<2413::AID-ANIE2413>3.0.CO
[35]  
2-H
[36]   A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: Novel ligand coordination [J].
Yin, JJ ;
Rainka, MP ;
Zhang, XX ;
Buchwald, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) :1162-1163
[37]   Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides [J].
Zapf, A ;
Jackstell, R ;
Rataboul, F ;
Riermeier, T ;
Monsees, A ;
Fuhrmann, C ;
Shaikh, N ;
Dingerdissen, U ;
Beller, M .
CHEMICAL COMMUNICATIONS, 2004, (01) :38-39