A Mild Hydrothermal Route to Fix Carbon Dioxide to Simple Carboxylic Acids

被引：87

作者：

He, Chao ^{[1
]}

Tian, Ge ^{[1
]}

Liu, Ziwei ^{[1
]}

Feng, Shouhua ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130021, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 04期

基金：

中国国家自然科学基金;

关键词：

CO2; HYDROGENATION; ORGANIC-COMPOUNDS; REDUCTION; METHANOL; CATALYSTS; TIO2; GAS;

D O I：

10.1021/ol9025414

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reduction of carbon dioxide (CO2) under mild hydrothermal conditions was carried out in the presence of iron nanoparticles, In this reaction system, the iron nanoparticles not only act as the reducing agent but also catalyze the reduction of CO2 to form formic acid and acetic acid.

引用

页码：649 / 651

页数：3

共 19 条

[1] A Cu/Zn/Al/Zr fibrous catalyst that is an improved CO2 hydrogenation to methanol catalyst
An, Xin
Li, Jinlu
Zuo, Yizan
Zhang, Qiang
Wang, Dezheng
Wang, Jinfu
[J]. CATALYSIS LETTERS, 2007, 118 (3-4) : 264 - 269
[2] [Anonymous], 2007, INTERGOVERNMENTAL PA
[3] Selective solar-driven reduction of CO2 to methanol using a catalyzed p-GaP based photoelectrochemical cell
Barton, Emily E.
Rampulla, David M.
Bocarsly, Andrew B.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (20) : 6342 - +
[4] Design of effective zeolite catalysts for the complete hydrogenation of CO2
Chan, B
Radom, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (16) : 5322 - 5323
[5] SUBMARINE THERMAL SPRINGS ON THE GALAPAGOS RIFT
CORLISS, JB
DYMOND, J
GORDON, LI
EDMOND, JM
HERZEN, RPV
BALLARD, RD
GREEN, K
WILLIAMS, D
BAINBRIDGE, A
CRANE, K
VANANDEL, TH
[J]. SCIENCE, 1979, 203 (4385) : 1073 - 1083
[6] CO2 hydrogenation to methanol on a YBa2Cu3O7 catalyst
Gao, LZ
Au, CT
[J]. JOURNAL OF CATALYSIS, 2000, 189 (01) : 1 - 15
[7] Abiogenic methane formation and isotopic fractionation under hydrothermal conditions
Horita, J
Berndt, ME
[J]. SCIENCE, 1999, 285 (5430) : 1055 - 1057
[8] Photocatalytic reduction of CO2 over TiO2 based catalysts
Koci, Kamila
Obalova, Lucie
Lacny, Zdenek
[J]. CHEMICAL PAPERS, 2008, 62 (01): : 1 - 9
[9] Hydrothermal vents and the origin of life
Martin, William
Baross, John
Kelley, Deborah
Russell, Michael J.
[J]. NATURE REVIEWS MICROBIOLOGY, 2008, 6 (11) : 805 - 814
[10] Chemical Recycling off Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons
Olah, George A.
Goeppert, Alain
Prakash, G. K. Surya
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (02) : 487 - 498

← 1 2 →