Third-order effect in solid-state NMR of quadrupolar nuclei

被引：29

作者：

Gan, ZH ^{[1
]}

Srinivasan, P

Quine, JR

Steuernagel, S

Knott, B

机构：

[1] NHMFL, Tallahassee, FL 32310 USA

[2] Florida State Univ, Dept Math, Tallahassee, FL 32306 USA

[3] Bruker Analyt GmbH, D-76287 Rheinstetten, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 367卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0009-2614(02)01681-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l = 6 and shifts NMR. frequencies between two spin states that are not symmetric such as satellite transitions. Two-dimensional satellite transition magic-angle spinning experiment averages both the first and the second-order quadrupolar interactions making the quantitative measurement of. the third-order effect possible. The third-order quadrupolar effect in andalusite has been measured at 11.7 T and its powder patterns are fitted with numerical simulations. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：163 / 169

页数：7

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