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Iodine as an efficient and available activator of sodium and potassium halides in carbon dioxide addition to epoxides
被引:6
作者:
Lyubimov, S. E.
[1
]
Zvinchuk, A. A.
[1
]
Chowdhury, B.
[2
]
机构:
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia
[2] Indian Sch Mines, Indian Inst Technol, Dept Chem, Dhanbad 826004, Bihar, India
基金:
俄罗斯科学基金会;
关键词:
alkaline metal halides;
iodine;
cyclic carbonates;
epoxides;
carbon dioxide;
CYCLIC CARBONATES;
ORGANIC CARBONATES;
CHEMICAL-REACTIONS;
CO2;
CATALYSTS;
POLYIODIDES;
WATER;
RAMAN;
KI;
D O I:
10.1007/s11172-021-3218-z
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Sodium and potassium halides in combination with molecular iodine are efficient catalysts for the solvent-free addition of CO2 (10-56 atm) to epoxides giving organic carbonates.
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页码:1324 / 1327
页数:4
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