Iodine as an efficient and available activator of sodium and potassium halides in carbon dioxide addition to epoxides

被引:6
作者
Lyubimov, S. E. [1 ]
Zvinchuk, A. A. [1 ]
Chowdhury, B. [2 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia
[2] Indian Sch Mines, Indian Inst Technol, Dept Chem, Dhanbad 826004, Bihar, India
基金
俄罗斯科学基金会;
关键词
alkaline metal halides; iodine; cyclic carbonates; epoxides; carbon dioxide; CYCLIC CARBONATES; ORGANIC CARBONATES; CHEMICAL-REACTIONS; CO2; CATALYSTS; POLYIODIDES; WATER; RAMAN; KI;
D O I
10.1007/s11172-021-3218-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sodium and potassium halides in combination with molecular iodine are efficient catalysts for the solvent-free addition of CO2 (10-56 atm) to epoxides giving organic carbonates.
引用
收藏
页码:1324 / 1327
页数:4
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