Silica-acetate complex of N2O4:: A heterogeneous reagent for the selective nitration of phenols and nitrosation of thiols

被引：21

作者：

Iranpoor, N ^{[1
]}

Firouzabadi, H ^{[1
]}

Heydari, R ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz 71454, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 05期

关键词：

D O I：

10.1081/SCC-120016310

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Complexation of gaseous N2O4 with acylated silica gel affords an addition compound, which is an efficient heterogeneous reagent for the selective mono- and dinitration of phenol, substituted phenols and nitrosation of thiols.

引用

页码：703 / 710

页数：8

共 31 条

[1]

[Anonymous], CHEM THIOL GROUP 2

[2] NITROSATION OF ANILINE BY N2O4 [J].

AZIZ, A ;

HOHARUM, M ;

KHALIL, MI .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :1737-1742

[3] NITROSAMINES FROM TERTIARY-AMINES AND DINITROGEN TETRAOXIDE [J].

BOYER, JH ;

PILLAI, TP .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1985, (08) :1661-1664

[4]

BRUICE TC, 1986, J AM CHEM SOC, V90, P1612

[5] CHEMISTRY OF NITROSO-COMPOUNDS .11. NITROSATION OF AMINES BY THE 2-PHASE INTERACTION OF AMINES IN SOLUTION WITH GASEOUS OXIDES OF NITROGEN [J].

CHALLIS, BC ;

KYRTOPOULOS, SA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (02) :299-304

[6]

CORNELIS A, 1994, SYNLETT, P155

[7] CLAY-SUPPORTED REAGENTS .4. A NOVEL COUPLING OF THIOLS INTO DISULFIDES, VIA THIONITRITE INTERMEDIATES USING A CLAY-SUPPORTED NITROSATION REAGENT [J].

CORNELIS, A ;

DEPAYE, N ;

GERSTMANS, A ;

LASZLO, P .

TETRAHEDRON LETTERS, 1983, 24 (30) :3103-3106

[8] Silica acetate complex of N2O4:: A highly efficient reagent for the selective conversion of thioethers to their corresponding sulfoxides [J].

Firouzabadi, H ;

Iranpoor, N ;

Heydari, R .

SYNTHETIC COMMUNICATIONS, 2001, 31 (13) :2037-2041

[9] RATES AND MECHANISMS OF REACTION OF NITROGEN-DIOXIDE WITH ALKENES IN SOLUTION [J].

GIAMALVA, DH ;

KENION, GB ;

CHURCH, DF ;

PRYOR, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) :7059-7063

[10] MOLECULAR ADDITION COMPOUNDS OF DINITROGEN TETROXIDE .5. THE TERNARY SYSTEM 1,4-DIOXANE TETRAHYDROPYRAN DINITROGEN TETROXIDE [J].

GIBBINS, BJ ;

EICHHORN, GL ;

SISLER, HH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (18) :4668-4671

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