Influence of the Temperature and 2,5-Dimethylfuran Concentration on Its Sooting Tendency

被引：29

作者：

Alexandrino, Katiuska ^{[1
]}

Salvo, Pablo ^{[1
]}

Millera, Angela ^{[1
]}

Bilbao, Rafael ^{[1
]}

Alzueta, Maria U. ^{[1
]}

机构：

[1] Univ Zaragoza, Aragon Inst Engn Res I3A, Dept Chem & Environm Engn, Rio Ebro Campus, Zaragoza 50018, Spain

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 2016年 / 188卷 / 4-5期

关键词：

2,5-Dimethylfuran; Flow reactor; Pyrolysis; Soot; THERMAL-DECOMPOSITION; DIESEL-ENGINE; COMBUSTION; PYROLYSIS; EMISSIONS; OXIDATION; HYDROCARBONS; CHEMISTRY; ACETYLENE; GROWTH;

D O I：

10.1080/00102202.2016.1138828

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The sooting tendency of 2,5-dimethylfuran (2,5-DMF), as a proposed fuel or fuel additive, has been studied in a flow reactor at different reaction temperatures (975, 1075, 1175, 1275, 1375, and 1475 K) and inlet 2,5-DMF concentrations (5000, 7500, and 15,000 ppm) under pyrolytic conditions. The quantification of soot and light gases has been done. Additionally, the experimental results of the light gases have been simulated with a detailed gas-phase chemical kinetic model. The experimental results indicate that the temperature has a great influence on both the soot and gas yields, as well as on the concentration of the light gases of pyrolysis. The inlet 2,5-DMF concentration influences the soot yield, whereas no significant effect is observed on the gas yield.

引用

页码：651 / 666

页数：16

共 39 条

[1] Impact of nitrogen oxides (NO, NO2, N2O) on the formation of soot [J].

Abian, Maria ;

Peribanez, Eduardo ;

Millera, Angela ;

Bilbao, Rafael ;

Alzueta, Maria U. .

COMBUSTION AND FLAME, 2014, 161 (01) :280-287

[2] Effect of different concentration levels of CO2 and H2O on the oxidation of CO: Experiments and modeling [J].

Abian, Maria ;

Gimenez-Lopez, Jorge ;

Bilbao, Rafael ;

Alzueta, Maria U. .

PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2011, 33 :317-323

[3] Novel aspects in the pyrolysis and oxidation of 2,5-dimethylfuran [J].

Alexandrino, Katiuska ;

Millera, Angela ;

Bilbao, Rafael ;

Alzueta, Maria U. .

PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2015, 35 :1717-1725

[4] Oxidation of methyl formate and its interaction with nitric oxide [J].

Alzueta, Maria U. ;

Aranda, Veronica ;

Monge, Fabiola ;

Millera, Angela ;

Bilbao, Rafael .

COMBUSTION AND FLAME, 2013, 160 (05) :853-860

[5] Kinetic modeling of soot formation with detailed chemistry and physics:: Laminar premixed flames of C2 hydrocarbons [J].

Appel, J ;

Bockhorn, H ;

Frenklach, M .

COMBUSTION AND FLAME, 2000, 121 (1-2) :122-136

[6] Group additivity in soot formation for the example of C-5 oxygenated hydrocarbon fuels [J].

Barrientos, Eduardo J. ;

Lapuerta, Magin ;

Boehman, Andre L. .

COMBUSTION AND FLAME, 2013, 160 (08) :1484-1498

[7] Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals [J].

Binder, Joseph B. ;

Raines, Ronald T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1979-1985

[8]

Castaldi MJ, 1996, TWENTY-SIXTH SYMPOSIUM (INTERNATIONAL) ON COMBUSTION, VOLS 1 AND 2, P693

[9] Experimental study on combustion and emission characteristics of a diesel engine fueled with 2,5-dimethylfuran-diesel, n-butanol-diesel and gasoline-diesel blends [J].

Chen, Guisheng ;

Shen, Yinggang ;

Zhang, Quanchang ;

Yao, Mingfa ;

Zheng, Zunqing ;

Liu, Haifeng .

ENERGY, 2013, 54 :333-342

[10] Experimental and kinetic modeling study of 2,5-dimethylfuran pyrolysis at various pressures [J].

Cheng, Zhanjun ;

Xing, Lili ;

Zeng, Meirong ;

Dong, Weile ;

Zhang, Feng ;

Qi, Fei ;

Li, Yuyang .

COMBUSTION AND FLAME, 2014, 161 (10) :2496-2511

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