Structural diversity and distinct photoluminescent properties of two new lanthanide-copper (I) frameworks based on mixed isonicontinate/oxalate ligands

被引：7

作者：

Kang, Yao ^{[1
]}

Wang, Fei ^{[1
]}

Zhang, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

关键词：

Lanthanide; Copper; Isonicontinate; Oxalate; Photoluminescence; COORDINATION POLYMER; LAYERED NETWORKS; ISONICOTINATE; CLUSTERS; CHAINS;

D O I：

10.1016/j.inoche.2010.04.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Although several heterometallic Ln(III)-Cu(I) compounds with mixed isonicotinate(IN)/oxalate(Ox) ligands are known, only one kind of framework structure is established to date. It is inconceivable for such a complex four-component system. Two new Ln(III)-Cu(I) compounds [DyCu(IN)(2)(Ox)center dot H2O](n) (1) and [EuCu(IN)(2) (Ox)center dot 3H(2)O](n) (2) with distinct structural features and photoluminescent properties are successfully synthesized under hydrothermal conditions. The results demonstrate the structural diversity of such a mixed four-component system. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：938 / 940

页数：3

共 24 条

[21] Strategies for enhancing photoluminescence of Nd3+ in liquid media [J].