Structural diversity and distinct photoluminescent properties of two new lanthanide-copper (I) frameworks based on mixed isonicontinate/oxalate ligands

被引：7

作者：

Kang, Yao ^{[1
]}

Wang, Fei ^{[1
]}

Zhang, Jian ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

关键词：

Lanthanide; Copper; Isonicontinate; Oxalate; Photoluminescence; COORDINATION POLYMER; LAYERED NETWORKS; ISONICOTINATE; CLUSTERS; CHAINS;

D O I：

10.1016/j.inoche.2010.04.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Although several heterometallic Ln(III)-Cu(I) compounds with mixed isonicotinate(IN)/oxalate(Ox) ligands are known, only one kind of framework structure is established to date. It is inconceivable for such a complex four-component system. Two new Ln(III)-Cu(I) compounds [DyCu(IN)(2)(Ox)center dot H2O](n) (1) and [EuCu(IN)(2) (Ox)center dot 3H(2)O](n) (2) with distinct structural features and photoluminescent properties are successfully synthesized under hydrothermal conditions. The results demonstrate the structural diversity of such a mixed four-component system. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：938 / 940

页数：3

共 24 条

[1]

Beeby A., 2002, DALTON T, P1923

[2] Linking two distinct layered networks of nanosized {Ln18} and {Cu24} wheels through isonicotinate ligands [J].

Cheng, Jian-Wen ;

Zhang, Jie ;

Zheng, Shou-Tian ;

Yang, Guo-Yu .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (01) :88-97

[3] A series of lanthanide-transition metal frameworks based on 1-, 2-, and 3D metal-organic motifs linked by different 1D copper(I) halide motifs [J].

Cheng, Jian-Wen ;

Zheng, Shou-Tian ;

Yang, Guo-Yu .

INORGANIC CHEMISTRY, 2007, 46 (24) :10261-10267

[4] Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction [J].

Cheng, Jian-Wen ;

Zheng, Shou-Tian ;

Yang, Guo-Yu .

DALTON TRANSACTIONS, 2007, (36) :4059-4066

[5] Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36}) wheels [J].

Cheng, JW ;

Zhang, J ;

Zheng, ST ;

Zhang, MB ;

Yang, GY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :73-77

[6] First 3D Pr(III)-Ni(II)-Na(I) polymer and a 3D Pr(III) open network based on pyridine-2,4,6-tricarboxylic acid [J].

Gao, HL ;

Yi, L ;

Ding, B ;

Wang, HS ;

Cheng, P ;

Liao, DZ ;

Yan, SP .

INORGANIC CHEMISTRY, 2006, 45 (02) :481-483

[7] Incorporating metal clusters into three-dimensional Ln(III)-Cu(I) coordination frameworks through linear Ligands [J].

Gu, Xiaojun ;

Xue, Dongfeng .

CRYSTAL GROWTH & DESIGN, 2007, 7 (09) :1726-1732

[8] 3D coordination framework [Ln4(μ3-OH)2Cu6I5(IN)8(OAc)3] (IN = isonicotinate):: Employing 2D layers of lanthanide wheel clusters and 1D chains of copper halide clusters [J].

Gu, Xiaojun ;

Xue, Dongfeng .

INORGANIC CHEMISTRY, 2007, 46 (13) :5349-5353

[9] Self-assembly of 3-D 4d-4f coordination frameworks based on 1-D inorganic heterometallic chains and linear organic linkers [J].

Gu, Xiaojun ;

Xue, Dongfeng .

CRYSTENGCOMM, 2007, 9 (06) :471-477

[10] Twofold interpenetration corrugated brick wall frameworks of 3d-4f heterometallic coordination polymers [J].

Huang, You-Gui ;

Wu, Min-Yan ;

Lian, Fen-Yan ;

Jiang, Fei-Long ;

Hong, Mao-Chun .

INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (08) :840-842

← 1 2 3 →