Syntheses and crystal structures of two ion pair complexes, [Ru(bpy)3]2[Fe(CN)6]I•7H2O and [Ru(bpy)3]-[Fe(CN)5NO]CH3OH•H2O

被引：6

作者：

Dong, W

Si, SF

Liao, DZ ^{[1
]}

Jiang, ZH

Yan, SP

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 06期

关键词：

crystal structures; ruthenium(II); H-bonding;

D O I：

10.1080/0095897031000101448

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two ion pair complexes, [Ru(bPY)(3)](2)[Fe(CN)(6)]1.7H(2)O (1) and [Ru(bpY)(3)][Fe(CN)(5)NO](CH3OH). H2O (2) (bpy = 2,2-bipyridine) have been synthesized and structurally characterized. X-Ray crystallographic structures of 1 and 2 both show Fe(III) and Ru(II) in distorted octahedral environments. In both complexes, H-bonding interactions between an uncoordinated water molecule and the nitrogen atom of a cyano group exist.

引用

页码：531 / 538

页数：8

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