Fantastic barocalorics and where to find them

被引:60
作者
Boldrin, David [1 ]
机构
[1] Univ Glasgow, Sch Phys & Astron, SUPA, Glasgow G12 8QQ, Lanark, Scotland
关键词
ROOM-TEMPERATURE; THERMAL-CONDUCTIVITY; CALORIC MATERIALS; TRANSITION; PEROVSKITE; PRESSURE; STORAGE; MECHANISM;
D O I
10.1063/5.0046416
中图分类号
O59 [应用物理学];
学科分类号
摘要
Barocaloric materials have the potential to offer greener and more efficient alternatives to conventional refrigerants that exploit vapor compression for cooling and heating applications. The barocaloric effect, a temperature change in response to hydrostatic pressure, is widespread in materials; however, only in the last few years have giant and colossal barocaloric effects approaching those of commercial hydrocarbon refrigerants been discovered. These barocaloric effects are associated with large changes in the degrees of freedom within the material and can take various forms. Here, we discuss this variety and categorize barocaloric materials based on the degree of freedom that underpins the barocaloric effects. We use this framework to identify material families to explore for potential barocalorics.
引用
收藏
页数:9
相关论文
共 84 条
[1]   Thermal conductivities of solid and liquid phases for neopentylglycol, aminomethylpropanediol and their binary alloy [J].
Akbulut, S. ;
Ocak, Y. ;
Keslioglu, K. ;
Marasli, N. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2009, 70 (01) :72-78
[2]   Enhancing the Heat Transfer in an Active Barocaloric Cooling System Using Ethylene-Glycol Based Nanofluids as Secondary Medium [J].
Aprea, Ciro ;
Greco, Adriana ;
Maiorino, Angelo ;
Masselli, Claudia .
ENERGIES, 2019, 12 (15)
[3]   Reversible and irreversible colossal barocaloric effects in plastic crystals [J].
Aznar, Araceli ;
Lloveras, Pol ;
Barrio, Maria ;
Negrier, Philippe ;
Planes, Antoni ;
Manosa, Lluis ;
Mathur, Neil D. ;
Moya, Xavier ;
Tamarit, Josep-Lluis .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (02) :639-647
[4]   Giant and Reversible Inverse Barocaloric Effects near Room Temperature in Ferromagnetic MnCoGeB0.03 [J].
Aznar, Araceli ;
Lloveras, Pol ;
Kim, Ji-Yeob ;
Stern-Taulats, Enric ;
Barrio, Maria ;
Lluis Tamarit, Josep ;
Sanchez-Valdes, Cesar F. ;
Sanchez Llamazares, Jose Luis ;
Mathur, Neil D. ;
Moya, Xavier .
ADVANCED MATERIALS, 2019, 31 (37)
[5]   Giant barocaloric effects over a wide temperature range in superionic conductor AgI [J].
Aznar, Araceli ;
Lloveras, Pol ;
Romanini, Michela ;
Barrio, Maria ;
Tamarit, Josep-Lluis ;
Cazorla, Claudio ;
Errandonea, Daniel ;
Mathur, Neil D. ;
Planes, Antoni ;
Moya, Xavier ;
Manosa, Lluis .
NATURE COMMUNICATIONS, 2017, 8
[6]   Antiferromagnetic spintronics [J].
Baltz, V. ;
Manchon, A. ;
Tsoi, M. ;
Moriyama, T. ;
Ono, T. ;
Tserkovnyak, Y. .
REVIEWS OF MODERN PHYSICS, 2018, 90 (01)
[7]   Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)3] perovskite under easily accessible pressures [J].
Bermudez-Garcia, Juan M. ;
Sanchez-Andujar, Manuel ;
Castro-Garcia, Socorro ;
Lopez-Beceiro, Jorge ;
Artiaga, Ramon ;
Senaris-Rodriguez, Maria A. .
NATURE COMMUNICATIONS, 2017, 8
[8]  
Boldrin D., BAROCALORIC PR UNPUB
[9]   Multisite Exchange-Enhanced Barocaloric Response in Mn3NiN [J].
Boldrin, David ;
Mendive-Tapia, Eduardo ;
Zemen, Jan ;
Staunton, Julie B. ;
Hansen, Thomas ;
Aznar, Araceli ;
Tamarit, Josep-Lluis ;
Barrio, Maria ;
Lloveras, Pol ;
Kim, Jiyeob ;
Moya, Xavier ;
Cohen, Lesley F. .
PHYSICAL REVIEW X, 2018, 8 (04)
[10]   Giant room-temperature barocaloric effects in PDMS rubber at low pressures [J].
Carvalho, A. M. G. ;
Imamura, W. ;
Usuda, E. O. ;
Bom, N. M. .
EUROPEAN POLYMER JOURNAL, 2018, 99 :212-221