A novel 18-membered metallocycle in {2,5-bis[3-(1H-1,3-imidazol-1-ylmethyl)phenyl]-1,3,4-oxadiazole}dichloridocobalt(II)

被引：0

作者：

Wu, Yan ^{[1
]}

Hou, Gui-Ge ^{[1
]}

Ma, Jian-Ping ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2010年 / 66卷

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; TRANSFORMATION; INCLUSION; CHEMISTRY; CRYSTAL;

D O I：

10.1107/S0108270110016689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title molecular complex, [CoCl(2)(C(22)H(18)N(6)O)], features a novel 18-membered Co-containing metallocycle. The Co(II) atom lies in a fairly regular tetrahedral geometry defined by two imidazole N-atom donors from one 2,5-bis[3-(1H-1,3-imidazol-1-ylmethyl)phenyl]-1,3,4-oxadiazole (L) ligand and two chloride anions. The coordinating orientation of the L ligand plays an important role in constructing the metallocycle complex. The complexes form a three-dimensional supramolecular assembly via nonclassical C-H center dot center dot center dot Cl and C-H center dot center dot center dot N hydrogen bonds and pi-pi interactions.

引用

页码：M163 / M165

页数：3

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