CuInSe2 thin films obtained by a novel electrodeposition and sputtering combined method

被引：16

作者：

Guillén, C ^{[1
]}

Martínez, MA ^{[1
]}

Herrero, J ^{[1
]}

机构：

[1] CIEMAT, Dept Energias Renovables, E-28040 Madrid, Spain

来源：

VACUUM | 2000年 / 58卷 / 04期

关键词：

CuInSe2; electrodeposition; sputtering;

D O I：

10.1016/S0042-207X(00)00355-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The combination of electrodeposited Cu-Se alloy and sputtered In precursors, followed by annealing in Se atmosphere, was found successful to obtain CuInSe2, thin films with Cu/In composition ratios varying between 0.25 and 2.75. Structural and morphological properties were observed to be dependent on annealing temperature and Cu/In ratio. When Cu/In > 1, both a CuInSe2, crystallinity improvement and a smooth surface were achieved. Apart from the ternary CuInSe2, two different binaries were detected: Cu2Se crystallises after 400 degrees C annealing in samples with Cu/In > 1, and In2Se3 does after annealing at 500 degrees C for the distinct Cu/In ratios considered. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：594 / 601

页数：8

共 17 条

[1]

ADURODIJA FO, 1998, P 2 WORLD C PHOT SOL, P488

[2] 12.3% efficient CuIn1-xGaxSe2-based device from electrodeposited precursor [J].

Bhattacharya, RN ;

Wiesner, H ;

Berens, TA ;

Matson, J ;

Keane, J ;

Ramanathan, K ;

Swartzlander, A ;

Mason, A ;

Noufi, RN .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) :1376-1379

[3]

CASTELEYN M, 1992, P 11 EUR PHOT SOL EN, P826

[4]

DIMMLER B, 1997, P 14 E C PHOT SOL EN, P2683

[5]

FORBES I, 1995, P 13 EUR PHOT SOL EN, P1965

[6]

Green MA, 1997, PROG PHOTOVOLTAICS, V5, P265, DOI 10.1002/(SICI)1099-159X(199707/08)5:4<265::AID-PIP177>3.0.CO

[7]

2-4

[8] Improved selenization procedure to obtain CuInSe2 thin films from sequentially electrodeposited precursors [J].

Guillen, C ;

Herrero, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (02) :493-498

[9] REACTION PATHWAYS TO CUINSE2 FORMATION FROM ELECTRODEPOSITED PRECURSORS [J].

GUILLEN, C ;

HERRERO, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) :1834-1838

[10]

HYLAND M, 1992, P 11 EUR PHOT SOL EN, P818

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