Bis(Nitroxymethylisoxazolyl) Furoxan: A Promising Standalone Melt-Castable Explosive

被引：36

作者：

Johnson, Eric C. ^{[1
]}

Sabatini, Jesse J. ^{[1
]}

Chavez, David E. ^{[2
]}

Wells, Lucille A. ^{[2
]}

Banning, Joseph E. ^{[1
]}

Sausa, Rosario C. ^{[3
]}

Byrd, Edward F. C. ^{[3
]}

Orlicki, Joshua A. ^{[4
]}

机构：

[1] US Army, Res Lab, CCDC, Energet Synth & Formulat Branch, Aberdeen Proving Ground, MD 21005 USA

[2] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[3] US Army, Res Lab, CCDC, Detonat Sci & Modeling Branch, Aberdeen Proving Ground, MD 21005 USA

[4] US Army, Res Lab, CCDC, Polymers Branch, Aberdeen Proving Ground, MD 21005 USA

来源：

CHEMPLUSCHEM | 2020年 / 85卷 / 01期

关键词：

cycloaddition reactions; energetic materials; explosives; furoxans; heterocycles;

D O I：

10.1002/cplu.201900710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and crystal structure of the heterocyclic explosive bis(nitroxymethylisoxazolyl) furoxan, C10H6N6O10, are described. In addition, we report its physical properties and theoretical performance. This material was found to exhibit standalone melt-castable explosive properties, with a melting point of 89.8 degrees C and an onset decomposition temperature of 193.8 degrees C. Bis(nitroxymethylisoxazolyl) furoxan features an insensitive behavior to impact, friction, and electrostatic discharge, with a calculated detonation pressure about 25 % higher than the state-of-the-art melt-castable explosive TNT.

引用

页码：237 / 239

页数：3

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