Molecular dynamics simulation of the dynamics of supercooled silica

被引:63
作者
Horbach, J [1 ]
Kob, W [1 ]
Binder, K [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Phys, D-55099 Mainz, Germany
来源
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES | 1998年 / 77卷 / 02期
关键词
D O I
10.1080/13642819808204955
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present the results of a large-scale computer simulation of supercooled silica. We find that at high temperatures the diffusion constants show a non-Arrhenius temperature dependence, whereas at low temperature this dependence is compatible with an Arrhenius law. We demonstrate that at low temperatures the intermediate scattering function shows a two-step relaxation behaviour and that it obeys the time-temperature superposition principle. We also discuss the wave-vector dependence of the non-ergodicity parameter and the time and temperature dependences of the non-Gaussian parameter.
引用
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页码:297 / 303
页数:7
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