Co intake mediated formation of ultrathin nanosheets of transition metal LDH-an advanced electrocatalyst for oxygen evolution reaction

被引:208
作者
Long, Xia [1 ]
Xiao, Shuang [1 ]
Wang, Zilong [1 ]
Zheng, Xiaoli [1 ]
Yang, Shihe [1 ]
机构
[1] Hong Kong Univ Sci & Technol, William Mong Inst Nano Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
关键词
WATER OXIDATION; SPECTROSCOPIC CHARACTERIZATION; ELECTROCHEMICAL EVOLUTION; ENHANCED ACTIVITY; OXIDE CATALYSTS; COBALT; FILM; FE; ELECTRODES; IRON;
D O I
10.1039/c4cc08856e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By controlling the ratio of tri- and bi-valent ions, multi-transition metal based layered double hydroxide (LDH) ultrathin nanosheets are synthesized. They show advanced OER performance with low overpotentials (similar to 0.2 V) and decreased Tafel slopes with increasing Co incorporation due to the modulated electronic structures of catalytic centers and the increased surface area and electronic conductivity.
引用
收藏
页码:1120 / 1123
页数:4
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  • [21] Nanoporous BiVO4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
    Kim, Tae Woo
    Choi, Kyoung-Shin
    [J]. SCIENCE, 2014, 343 (6174) : 990 - 994
  • [22] NiFe-oxide electrocatalysts for the oxygen evolution reaction on Ti doped hematite photoelectrodes
    Kleiman-Shwarsctein, Alan
    Hu, Yong-Sheng
    Stucky, Galen D.
    McFarland, Eric W.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (06) : 1150 - 1153
  • [23] Electrochemical and in situ Raman spectroscopic characterization of nickel hydroxide electrodes
    Kostecki, R
    McLarnon, F
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (02) : 485 - 493
  • [24] Spectroscopic Characterization of Mixed Fe-Ni Oxide Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Electrolytes
    Landon, James
    Demeter, Ethan
    Inoglu, Nilay
    Keturakis, Chris
    Wachs, Israel E.
    Vasic, Relja
    Frenkel, Anatoly I.
    Kitchin, John R.
    [J]. ACS CATALYSIS, 2012, 2 (08): : 1793 - 1801
  • [25] A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction
    Long, Xia
    Li, Jinkai
    Xiao, Shuang
    Yan, Keyou
    Wang, Zilong
    Chen, Haining
    Yang, Shihe
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (29) : 7584 - 7588
  • [26] An Investigation of Thin-Film Ni-Fe Oxide Catalysts for the Electrochemical Evolution of Oxygen
    Louie, Mary W.
    Bell, Alexis T.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (33) : 12329 - 12337
  • [27] Three-dimensional NiFe layered double hydroxide film for high-efficiency oxygen evolution reaction
    Lu, Zhiyi
    Xu, Wenwen
    Zhu, Wei
    Yang, Qiu
    Lei, Xiaodong
    Liu, Junfeng
    Li, Yaping
    Sun, Xiaoming
    Duan, Xue
    [J]. CHEMICAL COMMUNICATIONS, 2014, 50 (49) : 6479 - 6482
  • [28] Highly active hydrogen evolution catalysis from metallic WS2 nanosheets
    Lukowski, Mark A.
    Daniel, Andrew S.
    English, Caroline R.
    Meng, Fei
    Forticaux, Audrey
    Hamers, Robert J.
    Jin, Song
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (08) : 2608 - 2613
  • [29] Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
    Man, Isabela C.
    Su, Hai-Yan
    Calle-Vallejo, Federico
    Hansen, Heine A.
    Martinez, Jose I.
    Inoglu, Nilay G.
    Kitchin, John
    Jaramillo, Thomas F.
    Norskov, Jens K.
    Rossmeisl, Jan
    [J]. CHEMCATCHEM, 2011, 3 (07) : 1159 - 1165
  • [30] Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
    McCrory, Charles C. L.
    Jung, Suho
    Peters, Jonas C.
    Jaramillo, Thomas F.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (45) : 16977 - 16987