Co intake mediated formation of ultrathin nanosheets of transition metal LDH-an advanced electrocatalyst for oxygen evolution reaction

被引:210
作者
Long, Xia [1 ]
Xiao, Shuang [1 ]
Wang, Zilong [1 ]
Zheng, Xiaoli [1 ]
Yang, Shihe [1 ]
机构
[1] Hong Kong Univ Sci & Technol, William Mong Inst Nano Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
关键词
WATER OXIDATION; SPECTROSCOPIC CHARACTERIZATION; ELECTROCHEMICAL EVOLUTION; ENHANCED ACTIVITY; OXIDE CATALYSTS; COBALT; FILM; FE; ELECTRODES; IRON;
D O I
10.1039/c4cc08856e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By controlling the ratio of tri- and bi-valent ions, multi-transition metal based layered double hydroxide (LDH) ultrathin nanosheets are synthesized. They show advanced OER performance with low overpotentials (similar to 0.2 V) and decreased Tafel slopes with increasing Co incorporation due to the modulated electronic structures of catalytic centers and the increased surface area and electronic conductivity.
引用
收藏
页码:1120 / 1123
页数:4
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