Copper-catalyzed synthesis of unsymmetrical triarylphosphines

被引：138

作者：

Van Allen, D ^{[1
]}

Venkataraman, D ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 11期

关键词：

D O I：

10.1021/jo0343376

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various triarylphosphines have been prepared by coupling diphenylphosphine with aryl iodides with catalytic amounts of CuI in the presence of either K2CO3 or Cs2CO3, in good yields. This method can tolerate a variety of functional groups and does not require the use of expensive additives, or harsh reaction conditions, and is palladium free.

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页码：4590 / 4593

页数：4

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