Development of the surface structure of TRIP steels prior to hot-dip galvanizing

被引:108
作者
Bellhouse, E. M. [1 ]
Mertens, A. I. M. [1 ]
McDermid, J. R. [1 ]
机构
[1] McMaster Univ, Hamilton, ON L8S 4L7, Canada
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2007年 / 463卷 / 1-2期
基金
加拿大自然科学与工程研究理事会;
关键词
galvanizing; transformation-induced plasticity steel; gas-metal reactions; selective oxidation;
D O I
10.1016/j.msea.2006.09.117
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Focusing on improving the reactive wetting of transformation-induced plasticity (TRIP) steels during hot-dip galvanizing, the effect of the alloying elements manganese, silicon and aluminum on the surface structure prior to galvanizing was studied. A C-Mn steel and two TRIP steels with aluminum either completely or partially replacing silicon were investigated. The two TRIP steels showed good wettability when using a -30 degrees C dew point with a 95% N-2-5% H-2 atmosphere and improved wettability when using a -53 degrees C dew point with a 80% N-2-20% H-2 atmosphere. The decreased oxide thickness and the change in the distribution of oxides on the surface, showing a larger surface area that was free of oxide particles, contributed to the improved reactive wetting of the two TRIP steels at the -53 degrees C dew point. The C-Mn steel demonstrated excellent wettability for both annealing atmospheres. The observed reactive wetting was attributed to the reduction of MnO by Al in the Zn(Al, Fe) bath. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:147 / 156
页数:10
相关论文
共 36 条
[1]  
[Anonymous], 2002, IRON STEEL
[2]   X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES ON ZNS-MNF2 PHOSPHORS [J].
AOKI, A .
JAPANESE JOURNAL OF APPLIED PHYSICS, 1976, 15 (02) :305-311
[3]   Studies of the morphology of the Al-Rich interfacial layer formed during the hot dip galvanizing of steel sheet [J].
Baril, E ;
Lespérance, G .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1999, 30 (03) :681-695
[4]   PHOTOEMISSION-STUDY OF SIOX (0 LESS-THAN-OR-EQUAL-TO X LESS-THAN-OR-EQUAL-TO 2) ALLOYS [J].
BELL, FG ;
LEY, L .
PHYSICAL REVIEW B, 1988, 37 (14) :8383-8393
[5]  
BIRKS N, 1983, INTRO HIGH TEMPERATU, P41
[6]  
BORDIGNON L, 1998, GALVATECH, P260
[7]  
Briggs D., 2003, SURFACE ANAL AUGER X, P31
[8]   THE SURFACE-CHEMISTRY OF MANGANIFEROUS SILICATE MINERALS AS INFERRED FROM EXPERIMENTS ON TEPHROITE (MN2SIO4) [J].
CASEY, WH ;
HOCHELLA, MF ;
WESTRICH, HR .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1993, 57 (04) :785-793
[9]  
CHEN ZW, 1990, MATER SCI TECH SER, V6, P1173, DOI 10.1179/026708390790189939
[10]  
De Meyer M, 1999, ISIJ INT, V39, P813