Synthesis and post-metalation of a covalent-porphyrinic framework for highly efficient aerobic epoxidation of olefins

被引：20
作者：
Zhao, Min [1 ]
Wu, Chuan-De [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, State Key Lab Silicon Mat, Ctr Chem High Performance & Novel Mat, Hangzhou 310027, Zhejiang, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2017年 / 99卷
基金：
中国国家自然科学基金;
关键词：
Covalent-organic frameworks; Heterogeneous catalysis; Metalloporphyrin; Metal-organic frameworks; ORGANIC FRAMEWORKS; MOLECULAR-OXYGEN; CATALYSIS; OXIDATION; CONSTRUCTION; CRYSTALLINE; PLATFORM; PORES;
D O I：
10.1016/j.catcom.2017.06.001
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report a stable and porous 3D covalent-porphyrinic framework CPF-2, which is easily post-metalated with different metal ions to tune the catalytic properties. The cobalt(II) metalated material Co-CPF-2 exhibits high efficiency in heterogeneous catalysis of the aerobic epoxidation of olefins under mild conditions, in which > 99% conversion, 93% epoxide selectivity, 29,215 turnover number (TON) and 3434 h(-1) turnover frequency (TOF) have been realized for the aerobic epoxidation of styrene.
引用
收藏
页码：146 / 149
页数：4
相关论文
共 32 条
  • [1] Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal-Organic Framework: A Double Solvents Approach
    Aijaz, Arshad
    Karkamkar, Abhi
    Choi, Young Joon
    Tsumori, Nobuko
    Roennebro, Ewa
    Autrey, Tom
    Shioyama, Hiroshi
    Xu, Qiang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (34) : 13926 - 13929
  • [2] Beaudoin D, 2013, NAT CHEM, V5, P830, DOI [10.1038/NCHEM.1730, 10.1038/nchem.1730]
  • [3] Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene
    Colson, John W.
    Woll, Arthur R.
    Mukherjee, Arnab
    Levendorf, Mark P.
    Spitler, Eric L.
    Shields, Virgil B.
    Spencer, Michael G.
    Park, Jiwoong
    Dichtel, William R.
    [J]. SCIENCE, 2011, 332 (6026) : 228 - 231
  • [4] Covalent organic frameworks (COFs): from design to applications
    Ding, San-Yuan
    Wang, Wei
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (02) : 548 - 568
  • [5] Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki-Miyaura Coupling Reaction
    Ding, San-Yuan
    Gao, Jia
    Wang, Qiong
    Zhang, Yuan
    Song, Wei-Guo
    Su, Cheng-Yong
    Wang, Wei
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (49) : 19816 - 19822
  • [6] 3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery
    Fang, Qianrong
    Wang, Junhua
    Gu, Shuang
    Kaspar, Robert B.
    Zhuang, Zhongbin
    Zheng, Jie
    Guo, Hongxia
    Qiu, Shilun
    Yan, Yushan
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (26) : 8352 - 8355
  • [7] Covalent organic frameworks
    Feng, Xiao
    Ding, Xuesong
    Jiang, Donglin
    [J]. CHEMICAL SOCIETY REVIEWS, 2012, 41 (18) : 6010 - 6022
  • [8] Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal-Organic Frameworks
    Garzon-Tovar, Luis
    Rodriguez-Hermida, Sabina
    Imaz, Inhar
    Maspoch, Daniel
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (02) : 897 - 903
  • [9] Ikezoe Y, 2012, NAT MATER, V11, P1081, DOI [10.1038/NMAT3461, 10.1038/nmat3461]
  • [10] Constructing Ultraporous Covalent Organic Frameworks in Seconds via an Organic Terracotta Process
    Karak, Suvendu
    Kandambeth, Sharath
    Biswal, Bishnu P.
    Sasmal, Himadri Sekhar
    Kumar, Sushil
    Pachfule, Pradip
    Banerjee, Rahul
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) : 1856 - 1862
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