Developments of rare earth metal catalysts for olefin polymerization

被引:94
作者
Nakayama, Y [1 ]
Yasuda, H [1 ]
机构
[1] Hiroshima Univ, Grad Sch Med, Dept Appl Chem, Higashihiroshima 7398527, Japan
关键词
rare earth metals; polymerization; ethylene; alpha-olefins; cocatalysts;
D O I
10.1016/j.jorganchem.2004.05.056
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This review article describes recent developments in rare earth metal complexes as polymerization catalysts, focusing on the polymerization of ethylene and alpha-olefins. Most of this kind of catalysts had been based on metallocene type complexes, and their catalytic behaviors are surveyed. Advanced series of half-metallocene and non-Cp type catalyst systems are also summarized. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:4489 / 4498
页数:10
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