Developments of rare earth metal catalysts for olefin polymerization

被引：94
作者：
Nakayama, Y [1 ]
Yasuda, H [1 ]
机构：
[1] Hiroshima Univ, Grad Sch Med, Dept Appl Chem, Higashihiroshima 7398527, Japan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期
关键词：
rare earth metals; polymerization; ethylene; alpha-olefins; cocatalysts;
D O I：
10.1016/j.jorganchem.2004.05.056
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review article describes recent developments in rare earth metal complexes as polymerization catalysts, focusing on the polymerization of ethylene and alpha-olefins. Most of this kind of catalysts had been based on metallocene type complexes, and their catalytic behaviors are surveyed. Advanced series of half-metallocene and non-Cp type catalyst systems are also summarized. (C) 2004 Elsevier B.V. All rights reserved.
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收藏
页码：4489 / 4498
页数：10
相关论文
共 59 条
  • [1] Homogeneous ethylene-polymerization catalysts based on alkyl cations of the rare-earth metals: Are dicationic mono(alkyl) complexes the active species?
    Arndt, S
    Spaniol, TP
    Okuda, J
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (41) : 5075 - 5079
  • [2] Aubrecht KB, 2001, J POLYM SCI POL CHEM, V39, P284, DOI 10.1002/1099-0518(20010115)39:2<284::AID-POLA40>3.0.CO
  • [3] 2-C
  • [4] ALKYL BRIDGED COMPLEXES OF GROUP-3A AND LANTHANOID METALS AS HOMOGENEOUS ETHYLENE POLYMERIZATION CATALYSTS
    BALLARD, DGH
    COURTIS, A
    HOLTON, J
    MCMEEKING, J
    PEARCE, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (22) : 994 - 995
  • [5] Yttrium alkyl and benzyl complexes with amino-amidinate monoanionic ancillary ligands
    Bambirra, S
    Brandsma, MJR
    Brussee, EAC
    Meetsma, A
    Hessen, B
    Teuben, JH
    [J]. ORGANOMETALLICS, 2000, 19 (16) : 3197 - 3204
  • [6] Yttrium alkyl complexes with a sterically demanding benzamidinate ligand: synthesis, structure and catalytic ethene polymerisation
    Bambirra, S
    van Leusen, D
    Meetsma, A
    Hessen, B
    Teuben, JH
    [J]. CHEMICAL COMMUNICATIONS, 2003, (04) : 522 - 523
  • [7] Neutral and cationic yttrium alkyl complexes with linked 1,4,7-triazacyclononane-amide monoanionic ancillary ligands: synthesis and catalytic ethene polymerisation
    Bambirra, S
    van Leusen, D
    Meetsma, A
    Hessen, B
    Teuben, JH
    [J]. CHEMICAL COMMUNICATIONS, 2001, (07) : 637 - 638
  • [8] Bogaert S, 2000, MACROMOL CHEM PHYS, V201, P1813, DOI 10.1002/1521-3935(20000901)201:14<1813::AID-MACP1813>3.0.CO
  • [9] 2-B
  • [10] Lanthanidocene catalysts for the homo- and copolymerization of ethylene with butadiene
    Boisson, C
    Monteil, V
    Ribour, D
    Spitz, R
    Barbotin, F
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (14) : 1747 - 1754
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