Biomass derived phosphorous containing porous carbon material for hydrogen storage and high-performance supercapacitor applications

被引:67
作者
Ariharan, A. [1 ]
Ramesh, K. [3 ]
Vinayagamoorthi, R. [1 ,2 ]
Rani, M. Sandhya [4 ]
Viswanathan, B. [1 ]
Ramaprabhu, S. [4 ]
Nandhakumar, V [5 ]
机构
[1] Indian Inst Technol Madras, Natl Ctr Catalysis Res NCCR, Dept Chem, Chennai 600036, Tamil Nadu, India
[2] Anna Univ, Dept Chem, Chennai 600025, Tamil Nadu, India
[3] Poompuhar Coll Autonomous, Dept Chem, Melaiyur 609107, India
[4] Indian Inst Technol Madras, Nano Funct Mat Technol Ctr NFMTC, Dept Phys, Alternat Energy & Nanotechnol Lab AENL, Chennai 600036, Tamil Nadu, India
[5] AVVM Sri Pushpam Coll Autonomous Poondi, PG & Res Dept Chem, Thanjavur 613503, India
关键词
Biomass carbon; Heteroatoms; Porosity; Hydrogen storage; Supercapacitors; HIGH-SURFACE-AREA; OXYGEN REDUCTION; ACTIVATED CARBON; ENERGY-STORAGE; ELECTRODE MATERIAL; DOPED CARBON; NANOSTRUCTURED CARBON; MESOPOROUS CARBONS; NANOPOROUS CARBON; PEANUT SHELL;
D O I
10.1016/j.est.2020.102185
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Here in we report a facile method of self-phosphorous doped porous carbon by a simple carbonization route (without using any activation process) under argon gas atmosphere. The as-prepared material with high surface area of 756 m(2) g(-1) shown high H-2 storage capacity of-1.75 wt% at 298 K and 100 bars. Also, it exhibited a high specific capacitance of 253 Fg(-1) at the current density of 1 A g(-1). Further, it also showed the capacitive retention of similar to 95% at the current density of 5 A g(-1) for 10,000 cycles. Interestingly, a carbon material with porous structure is predominantly inspiring as they are cost-effective and ease to synthesis for industrial applications. Biomass derived self-phosphorous doped porous carbon is considered as a superior material for supercapacitor and hydrogen storage applications. It is shown high performance for both the applications, due to its exceptional chemical stability, conductivity, micro-meso porosity, high specific surface area, cost-effectiveness and sustainability.
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页数:11
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