Synthesis and mesomorphic behaviour of unsymmetrical tetracatenar [1,2,3]-triazole derivatives

被引:9
作者
Benallou, Soraya [1 ]
Saidi-Besbes, Salima [1 ]
Grelet, Eric [2 ]
Bentaleb, Ahmed [2 ]
Elaissari, Abdelhamid [3 ]
Agusti, Geraldine [3 ]
Derdour, Aicha [1 ]
机构
[1] Univ Oran 1 Ahmed Benbella, Fac Sci Exactes & Appl, Dept Chim, Lab Synth Organ Appl, BP1524 ELMnaouer, Oran 31000, Algeria
[2] Univ Bordeaux, CNRS UPR 8641, Ctr Rech Paul Pascal, F-33600 Pessac, France
[3] Univ Lyon 1, CNRS, UMR 5007, LAGEP CPE, F-69622 Villeurbanne, France
关键词
1; 2; 3-triazole; XRD; columnar mesophase; Tetracatenar mesogen; lamellar crystal; CLICK CHEMISTRY; LIQUID-CRYSTALS; MOLECULES; CORE; TRIAZOLE; ROD;
D O I
10.1080/02678292.2015.1124463
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New nonsymmetric four-chained and three-chained [1,2,3]-triazole derivatives were synthesised. Their phase behaviours were investigated by differential scanning calorimetry, polarised optical microscopy and X-ray diffraction analyses. The tetracatenar derivatives show a columnar mesophase and a lamellar crystalline phase. The effects of the length of the terminal alkoxy chain and the nature of the terminal group attached to the side phenyltriazole unit of the mesogenic core are discussed.
引用
收藏
页码:505 / 516
页数:12
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