New oxazoline-containing phosphoramidite ligand for palladium-catalyzed asymmetric allylic sulfonylation

被引：16
|
作者：
Gavrilov, KN
Bondarev, OG
Tsarev, VN
Shiryaev, AA
Lyubimov, SE
Kucherenko, AS
Davankov, VA
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] SA Esenin Ryazan State Pedag Univ, Ryazan 390000, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2003年 / 52卷 / 01期
关键词：
P; N-ligands; chiral phosphoramidites; palladium; rhodium; asymmetric allylic sulfonylation;
D O I：
10.1023/A:1022448432030
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New chiral oxazoline-containing phosphoramidite was synthesized and its complex formation with rhodium(I) and palladium(II) was examined. The new ligand is a highly efficient chiral inductor (ee up to 92%) in palladium-catalyzed asymmetric sulfonylation of 1,3-diphenylallyl acetate with sodium p-toluenesulfinate.
引用
收藏
页码：122 / 125
页数：4
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