Solution-Processable Glass LiI-Li4SnS4 Superionic Conductors for All-Solid-State Li-Ion Batteries

被引：276

作者：

Park, Kern Ho ^{[1
,2
]}

Oh, Dae Yang ^{[1
]}

Choi, Young Eun ^{[1
]}

Nam, Young Jin ^{[1
]}

Han, Lili ^{[3
]}

Kim, Ju-Young ^{[4
]}

Xin, Huolin ^{[3
]}

Lin, Feng ^{[5
]}

Oh, Seung M. ^{[2
]}

Jung, Yoon Seok ^{[1
]}

机构：

[1] UNIST, Dept Energy Engn, Sch Energy & Chem Engn, Ulsan 689798, South Korea

[2] Seoul Natl Univ, Sch Chem & Biol Engn, 599 Gwanangno, Seoul 151742, South Korea

[3] Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11973 USA

[4] UNIST, Mat Sci & Engn, Ulsan 689798, South Korea

[5] Lawrence Berkeley Natl Lab, Energy Storage & Distributed Resources Div, Berkeley, CA 94720 USA

来源：

ADVANCED MATERIALS | 2016年 / 28卷 / 09期

基金：

新加坡国家研究基金会;

关键词：

LITHIUM SECONDARY BATTERIES; THIO-LISICON; RECHARGEABLE BATTERIES; ELECTRODE MATERIALS; CONDUCTIVITY; CHALLENGES; SYSTEMS; STORAGE; LICOO2; FILM;

D O I：

10.1002/adma.201505008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new, highly conductive (4.1 × 10-4 S cm-1 at 30 °C), highly deformable, and dry-air-stable glass 0.4LiI-0.6Li4SnS4 is prepared using a homogeneous methanol solution. The solution process enables the wetting of any exposed surface of the active materials with highly conductive solidified electrolytes (0.4LiI-0.6Li4SnS4), resulting in considerable improvements in the electrochemical performance of these electrodes over conventional mixture electrodes. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1874 / 1883

页数：10

共 52 条

[1] A New Approach to Develop Safe All-Inorganic Monolithic Li-Ion Batteries [J].

Aboulaich, Abelmaula ;

Bouchet, Renaud ;

Delaizir, Gaelle ;

Seznec, Vincent ;

Tortet, Laurence ;

Morcrette, Mathieu ;

Rozier, Patrick ;

Tarascon, Jean-Marie ;

Viallet, Virginie ;

Dolle, Mickael .

ADVANCED ENERGY MATERIALS, 2011, 1 (02) :179-183

[2] Building better batteries [J].

Armand, M. ;

Tarascon, J. -M. .

NATURE, 2008, 451 (7179) :652-657

[3]

Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]

[4] Thermodynamic model for solid-state amorphization in binary systems at interfaces and grain boundaries [J].

Benedictus, R ;

Bottger, A ;

Mittemeijer, EJ .

PHYSICAL REVIEW B, 1996, 54 (13) :9109-9125

[5] Fast Lithium Ion Conduction in Li2SnS3: Synthesis, Physicochemical Characterization, and Electronic Structure [J].

Brant, Jacilynn A. ;

Massi, Danielle M. ;

Holzwarth, N. A. W. ;

MacNeil, Joseph H. ;

Douvalis, Alexios P. ;

Bakas, Thomas ;

Martin, Steve W. ;

Gross, Michael D. ;

Aitken, Jennifer A. .

CHEMISTRY OF MATERIALS, 2015, 27 (01) :189-196

[6] Li10SnP2S12: An Affordable Lithium Superionic Conductor [J].

Bron, Philipp ;

Johansson, Sebastian ;

Zick, Klaus ;

auf der Guenne, Joern Schmedt ;

Dehnen, Stefanie ;

Roling, Bernhard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (42) :15694-15697

[7]

Bruce P.G., 1995, Solid state electrochemistry, V1st

[8] Li6PS5X:: A class of crystalline Li-rich solids with an unusually high Li+ mobility [J].

Deiseroth, Hans-Joerg ;

Kong, Shiao-Tong ;

Eckert, Hellmut ;

Vannahme, Julia ;

Reiner, Christof ;

Zaiss, Torsten ;

Schlosser, Marc .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (04) :755-758

[9] Structural and Mechanistic Insights into Fast Lithium-Ion Conduction in Li4SiO4-Li3PO4 Solid Electrolytes [J].

Deng, Yue ;

Eames, Christopher ;

Chotard, Jean-Noel ;

Lalere, Fabien ;

Seznec, Vincent ;

Emge, Steffen ;

Pecher, Oliver ;

Grey, Clare P. ;

Masquelier, Christian ;

Islam, M. Saiful .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (28) :9136-9145

[10] Positive Electrode Materials for Li-Ion and Li-Batteries [J].

Ellis, Brian L. ;

Lee, Kyu Tae ;

Nazar, Linda F. .

CHEMISTRY OF MATERIALS, 2010, 22 (03) :691-714

← 1 2 3 4 5 6 →