A facile stereoselective synthesis of (Z)-1,3-diaryl-2-(N-methylanilino)-2-propen-1-ones

被引：9

作者：

Srinivasan, M. ^{[1
]}

Perumal, S. ^{[1
]}

Selvaraj, S. ^{[1
]}

机构：

[1] Madurai Kamaraj Univ, Sch Chem, Dept Organ Chem, Madurai 625021, Tamil Nadu, India

来源：

ARKIVOC | 2006年

关键词：

1-ethanones; 2-propen-1-ones; configuration; NMR spectroscopic data; NOE; stereoselective synthesis;

D O I：

10.3998/ark.5550190.0007.a03

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Claisen-Schmidt condensation of 1-aryl-2-(N-methylanilino)-1-ethanones with aromatic aldehydes in the presence of sodium hydroxide in aqueous alcohol led to the formation of hitherto unknown (Z)-1,3-diaryl-2-(N-methylanilino)-2-propen-1-ones. The structure and stereochemistry of the products were elucidated from H-1, C-13 and 2D NMR spectroscopic data and nuclear Overhauser effect.

引用

页码：21 / 27

页数：7

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