Single-crystal structure determination of a new polymorph (ε-Alq3) of the electroluminescence OLED (organic light-emitting diode) material, tris(8-hydroxyquinoline)aluminum (Alq3)

被引：34

作者：

Rajeswaran, M ^{[1
]}

Blanton, TN ^{[1
]}

机构：

[1] Eastman Kodak Co, Res & Dev Labs, Rochester, NY 14650 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2005年 / 35卷 / 01期

关键词：

crystal structure; Alq3; OLED; 8-hydroxyquinoline;

D O I：

10.1007/s10870-005-1157-4

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Tris(8-hydroxyquinoline) aluminum, Alq(3), is the most widely used electroluminescent material in organic light-emitting diode (OLED), chemistry. Single-crystal structure determination of a new polymorph of Alq(3), designated as epsilon-Alq(3), is described. There are three molecules of Alq(3) in the asymmetric unit. This octahedrally coordinated complex crystallizes in the triclinic space group P-1, lattice parameters a = 13.5190(5) Angstrom, b = 15.8550(6) Angstrom, c = 18.7110(8) Angstrom, alpha = 95.4940(19)degrees, beta = 109.774(2)degrees, gamma = 114.6270(16)degrees, Volume = 3296.8(2) Angstrom(3), Z = 6, Z' = 3.

引用

页码：71 / 76

页数：6

共 16 条

[1] Correlation between molecular packing and optical properties in different crystalline polymorphs and amorphous thin films of mer-tris(8-hydroxyquinoline)aluminum(III) [J].

Brinkmann, M ;

Gadret, G ;

Muccini, M ;

Taliani, C ;

Masciocchi, N ;

Sironi, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (21) :5147-5157

[2]

*BRUK AN XRAY SYST, 2003, SHELXTL STRUCT AN SO

[3] The structure of the blue luminescent δ-phase of tris(8-hydroxyquinoline)aluminium(III) (Alq3) [J].

Cölle, M ;

Dinnebier, RE ;

Brütting, W .

CHEMICAL COMMUNICATIONS, 2002, (23) :2908-2909

[4] Crystal structure of tris(8-quinolinolato)aluminum(III) ethyl acetate(1/0.5) [J].

Fujii, I ;

Hirayama, N ;

Ohtani, J ;

Kodama, K .

ANALYTICAL SCIENCES, 1996, 12 (01) :153-154

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF THE ETHANOL ADDUCT OF TRIS(OXINATO)INDIUM(III) [J].

KORBER, N ;

ACHOUR, B ;

NEPVEU, F .

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1994, 24 (10) :685-688

[6]

*MAT DAT INC, 2001, JPOWD

[7]

*NON, 2001, KAPPACCD

[8] Tris(quinolin-8-olato)gallium(III) [J].

Rajeswaran, M ;

Jarikov, VV .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 :M217-M218

[9] Tris(quinolin-8-olato)indium(III) [J].

Rajeswaran, M ;

Jarikov, VV .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M306-M307

[10]

RAJESWARAN M, 2003, Z KRIST-NEW CRYST ST, V218, P1

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