Many-body formalism for thermally excited wave packets: A way to connect the quantum regime to the classical regime

被引:5
作者
Chenu, Aurelia [1 ,2 ]
Combescot, Monique [3 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] Singapore MIT Alliance Res & Technol, Singapore 138602, Singapore
[3] Univ Paris 06, CNRS, Inst NanoSci Paris, 4 Pl Jussieu, F-75005 Paris, France
基金
瑞士国家科学基金会;
关键词
D O I
10.1103/PhysRevA.95.062124
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Free classical particles have well-defined momentum and position, while free quantum particles have well-defined momentum but a position fully delocalized over the sample volume. We develop a many-body formalism based on wave-packet operators that connects these two limits, the thermal energy being distributed between the state spatial extension and its thermal excitation. The corresponding mixed quantum-classical states, which render the Boltzmann operator diagonal, are the physically relevant states when the temperature is finite. The formulation of many-body Hamiltonians in terms of these thermally excited wave packets and the resulting effective scatterings is provided.
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页数:8
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