Arylation reaction of N-dichlorophosphoryl-P-trichlorophosphazene

被引：18
作者：
Arslan, M [1 ]
Aslan, F
Ozturk, AI
机构：
[1] Harran Univ, Dept Chem, TR-63100 Sanliurfa, Turkey
[2] Firat Univ, Dept Chem, TR-23169 Elazig, Turkey
来源：
HETEROATOM CHEMISTRY | 2003年 / 14卷 / 02期
关键词：
PHOSPHORUS-NITROGEN COMPOUNDS; CHAIN LINEAR PHOSPHAZENES; BLOCK-COPOLYMERS; CRYSTAL-STRUCTURE; SIDE GROUPS; AMINOLYSIS; POLYMERIZATION; CHEMISTRY;
D O I：
10.1002/hc.10114
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of N-dichlorophosphoryl-P-trichlorophosphazene (Cl3P=N-POCl2) with phenylmagnesium chloride, o-tolylmagnesium chloride, p-tolylmagnesium chloride, p-chlorophenylmagnesium chloride, 2-mesitylmagnesium bromide, and 2-thienyl lithium were studied. The resulting pentaaryl phosphazenes R3P=N-P(O)R-2 were separated by using column chromatography, their structures were defined by IR, elemental analysis, H-1, C-13, P-31 NMR, and mass spectroscopy. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码：138 / 143
页数：6
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