Oxidation behavior of a single-crystal Ni-base superalloy in air -: II:: At 1000, 1100, and 1150°C

被引:82
作者
Li, MH [1 ]
Sun, XF [1 ]
Jin, T [1 ]
Guan, HR [1 ]
Hu, ZQ [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
来源
OXIDATION OF METALS | 2003年 / 60卷 / 1-2期
关键词
single-crystal Ni-base superalloy; oxidation; kinetics; microstructure;
D O I
10.1023/A:1024629716452
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The oxidation behavior of a single-crystal (SC) Ni-base superalloy was studied over the temperature range from 1000-1150degrees C and analysed by TGA, XRD, EDAX, and SEM. The results indicated that the SC Ni-base superalloy exhibited parabolic oxidation kinetics, which were controlled by the growth of the inner alpha-Al2O3 layer. A mixed scale formed on the SC Ni-base superalloy after prolonged oxidation. The scale consisted of an outer layer of spinel, a sublayer of mainly alpha-Al2O3 with small amount of spinel adjoined by a very thin and even discontinuous layer of CrTaO4-rich oxide, and an inner alpha-Al2O3 layer. The inner alpha-Al2O3 layer provided good protection. No internal oxides or nitrides were observed below the inner alpha-Al2O3 layer after 1000 hr at 1000degrees C, and after 200 hr at 1100 and 1150degrees C.
引用
收藏
页码:195 / 210
页数:16
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