Macrocyclic and lantern complexes of bis(amidopyridine) ligands: Synthesis, palladium(II) with structure, and host-guest chemistry

被引:111
作者
Yue, NLS [1 ]
Eisler, DJ [1 ]
Jennings, MC [1 ]
Puddephatt, RJ [1 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
关键词
D O I
10.1021/ic048893+
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactions of [PdCl2(NCPh)(2)] in a 1:1 ratio with the bis(amidopyridine) ligands LL = C6H3(5-R)(1,3-CONH-3-C5H4N)(2) with R = H (1a) or R = t-Bu (1b) give the corresponding neutral dipalladium(II) macrocycles trans,trans-[Pd2Cl4(mu-LL)(2)], 2a and 2b, which crystallize from dimethylformamide with one or two solvent molecules as macrocycle guests. The reaction of [PdCl2(NCPh)(2)] with LL in a 1:2 ratio gave the cationic lantern complex [Pd-2(mu-LL)(4)]Cl-4, 3c (LL = 1b), and the reaction in the presence of AgO2CCF3 gave the corresponding trifluoroacetate salts [Pd-2(mu-LL)(4)](CF3CO2)(4), 3a (LL = 1a) and 3b (LL = 1b). These lantern complexes exhibit a remarkable host-guest chemistry, as they can encapsulate cations, anions, and water molecules by interaction of the guest with either the electrophilic NH or the nucleophilic C=O substituents of the amide groups, which can be directed toward the center of the lantern through easy conformational change. The structures of several of these host-guest complexes were determined, and it was found that the cavity size and shape vary according to the ligand conformation, with (PdPd)-Pd-... separations in the range from 9.45 to 11.95 Angstrom. Supramolecular ordering of the lanterns was observed in the solid state, through either hydrogen bonding or secondary bonding to the cationic palladium(II) centers. The selective inclusion by the lantern complexes of alkali metal ions in the sequence Na+ much greater than K+ much greater than Li+ was observed by ESI-MS.
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页码:7671 / 7681
页数:11
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