Thermoplastic Polyurethane Elastomer/Thermoplastic Polyolefin Elastomer Blends Compatibilized with a Polyolefinic Segment in TPU

被引:20
作者
Kim, Tae Kyoon [2 ]
Kim, Byung Kyu [1 ]
Lee, Sang Yun [3 ]
Cho, Yang Lae [3 ]
Kim, Min Seok [4 ]
Jeong, Han Mo [4 ]
机构
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, Pusan 609735, South Korea
[2] Hwaseung T&C Corp, Res Ctr, Gyoungnam 626220, South Korea
[3] Hosung Chemex Co Ltd, Ulsan R&D Ctr, Ulsan 689821, South Korea
[4] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea
关键词
TPU; TPO; blend; hydrogenated polybutadiene; compatibility; MECHANICAL-PROPERTIES; MODIFIED TPOS; PART I; MORPHOLOGY; POLYPROPYLENE; ADHESION; POLYMER; POLYCARBONATE; RHEOLOGY;
D O I
10.1007/s13233-009-0165-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of incorporating a hydrogenated polybutadiene segment (HPB) in a thermoplastic polyurethane elastomer (TPU) on the compatibility of TPU with a thermoplastic polyolefin elastomer (TPO) was examined. Scanning electron microscopy showed that the particle size of the dispersed phase in the TPU/TPO blends decreased with increasing HPB concentration in TPUs due to the compatibilizing effect of HPB. The crystallization behavior, tensile properties, and rheological properties of the blend also showed that the HPB present in TPUs enhanced the compatibility between TPU and TPO.
引用
收藏
页码:177 / 184
页数:8
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