Conventional synthesis methods of short-chain dialkylcarbonates and novel production technology via direct route from alcohol and waste CO2

被引:88
作者
Leino, E. [1 ]
Maki-Arvela, P. [1 ]
Eta, V. [1 ]
Murzin, D. Yu. [1 ]
Salmi, T. [1 ]
Mikkola, J. -P. [1 ,2 ]
机构
[1] Abo Akad Univ, Proc Chem Ctr, Lab Ind Chem & React Engn, SF-20500 Turku, Finland
[2] Umea Univ, Chem Biol Ctr, Dept Chem, SE-90187 Umea, Sweden
基金
芬兰科学院;
关键词
Dimethyl carbonate; Diethyl carbonate; Carbon dioxide; Zirconia; Palladium-copper chloride; DIMETHYL CARBONATE SYNTHESIS; HIGH-YIELD SYNTHESIS; DIETHYL CARBONATE; OXIDATIVE CARBONYLATION; PROPYLENE CARBONATE; CATALYTIC-PROPERTIES; COORDINATION CHEMISTRY; SELECTIVE SYNTHESIS; ZIRCONIA CATALYSTS; ELECTRON-TRANSFER;
D O I
10.1016/j.apcata.2010.05.046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The aim of this work is to review different synthesis methods of dialkylcarbonates with special emphasis on diethyl carbonate synthesis methodologies. The novel synthesis route for dimethyl carbonate and diethyl carbonate based on the utilization of alcohol and carbon dioxide as the raw materials, together with heterogeneous catalysts, is presented. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 13
页数:13
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