Dinitrogen activation by group 4 metal complexes

被引：74
作者：
Ohki, Yasuhiro
Fryzuk, Michael D.
机构：
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 18期
关键词：
coordination modes; dinitrogen; hafnium; nitrogen fixation; zirconium; SIDE-ON; MOLECULAR NITROGEN; BOND FORMATION; END-ON; PHOSPHINE COMPLEX; TERMINAL ALKYNES; N-2; ZIRCONIUM; REDUCTION; FUNCTIONALIZATION;
D O I：
10.1002/anie.200605245
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Side-on matters: When dinitrogen bridges two Group 4 metal centers in the side-on binding mode, the reactivity of the N2 unit is enhanced, as evidenced by unprecedented reactions with H2, alkynes, silanes, isocyanates, and now carbon dioxide (see scheme). This Highlight summarizes a number of recent breakthroughs in dinitrogen functionalization by bimetallic Group 4 complexes, culminating with the reaction of CO2 with a dihafium dinitrogen derivative. (Chemical Equation Presented) © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：3180 / 3183
页数：4
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