Structural probing of D-fructose derived ligands for asymmetric addition of diethylzinc to aldehydes

被引：32
|
作者：
Huang, HM [1 ]
Chen, HL [1 ]
Hu, XQ [1 ]
Bai, CM [1 ]
Zheng, Z [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
来源：
TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 03期
关键词：
D O I：
10.1016/S0957-4166(02)00861-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of new chiral ligands derived from D-fructose have been synthesized and applied in the enantioselective addition of diethylzinc to aldehydes. Comparison of the enantioselectivities obtained with these ligands demonstrated that the catalytic properties are highly dependent upon the structure of ligands, a rational explanation of the structural effects on the catalytic properties is provided. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：297 / 304
页数：8
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