Air/Water Interfacial Formation of Freestanding, Stimuli-Responsive, Self-Healing Catecholamine Janus-Faced Microfilms

被引:117
作者
Hong, Seonki [1 ]
Schaber, Clemens F. [2 ]
Dening, Kirstin [2 ]
Appel, Esther [2 ]
Gorb, Stanislav N. [2 ]
Lee, Haeshin [1 ,3 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Univ Kiel, Zool Inst Funct Morphol & Biomech, Kiel, Germany
[3] Korea Adv Inst Sci & Technol, Ctr Nat Inspired Technol, KI NanoCentury, Taejon 305701, South Korea
基金
新加坡国家研究基金会;
关键词
SURFACE-CHEMISTRY; HEMOLYMPH; HYDROGELS; COATINGS; POLYMER;
D O I
10.1002/adma.201403259
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A catecholamine freestanding film is discovered to be spontaneously formed at the air-water interface, and the film has unique properties of robust surface adhesiveness, self-healing, and stimuli-responsive properties. The interfacial film-producing procedure is a simple single step containing polyamines and catechol(amine)s. It is found that oxygen-rich regions existing at an air-water interface greatly accelerate the catecholamine crosslinking reaction. (Figure Presented). © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7581 / 7587
页数:7
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